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- W2570009323 abstract "Two thiophene-based and carbazole-based conjugated microporous polymers (PTPATTh and PTPATCz) with triphenylamine core structural monomers were synthesized via straight forward anhydrous ferric chloride oxidative coupling polymerization. We first explored the fluorescent sensing performance of thienyl CMPs for picric acid (PA) and investigated comparatively the porosity and fluorescence sensing property for PA/p-nitrophenol (NP). Thanks to the propeller-like structure, high porosity, extended π-conjugation and electron-rich characteristics, the both CMPs exhibited strong fluorescent emission properties and worked as fluorescent chemosensors toward electron-deficient nitroaromatic analytes. The suspension of PTPATTh and PTPATCz given rise to the high luminescence, and showed a white and yellow emission in both THF and DOX excited under 365 nm using a UV lamp, respectively. Though BET surface area values and response speed of PTPATTh (594 m2 g−1) are lower than that of PTPATCz (894 m2 g−1), PTPATTh display higher selectivity for tracing PA than PTPATCz in DOX and THF. In short, the PTPATTh may be a new kind of material for detecting PA." @default.
- W2570009323 created "2017-01-13" @default.
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- W2570009323 date "2017-06-01" @default.
- W2570009323 modified "2023-10-13" @default.
- W2570009323 title "Poly{tris[4-(2-Thienyl)phenyl]amine} fluorescent conjugated microporous polymer for selectively sensing picric acid" @default.
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- W2570009323 doi "https://doi.org/10.1016/j.snb.2017.01.005" @default.
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