Matches in SemOpenAlex for { <https://semopenalex.org/work/W2570206581> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W2570206581 endingPage "317" @default.
- W2570206581 startingPage "301" @default.
- W2570206581 abstract "Temperature-programmed desorption mass spectrometry (TPDMS) is discussed with reference to studies of modified pyrogenic oxides. Simple theoretical models are presented in order to allow an approximate analytical treatment of TPDMS data. The ‘unimolecular’ decomposition of alkoxide groups was studied. The rate constants of the reactions were derived from TPDMS measurements. The kinetics of thermal transformations of phosphorous and phosphoric acids on a pyrogenic silica surface were investigated by TPDMS. Oxidation–reduction reactions in samples containing phosphorous acid resulted in the removal of molecular phosphorus (P 4 ). Two stages of phosphorus evolution were observed which were attributed to the disproportion of phosphorus in the surface monolayer (high-temperature stage) and in the bulk layers (low-temperature stage). The biologically active samples obtained by adsorption of cyanocobalamine, glucose and raffinose on ultrafine oxide surfaces were studied via a combination of temperature-programmed desorption and solid-state thermal analysis mass spectrometry (TPD/TA MS). The role of the charged cobalt atom and of the propionamide and benzimide groups in the adsorption mechanism is discussed. It was shown that the adsorption of cyanocobalamine on the silica surface transformed the propionamide group to a weakly bound form. TPD/TA MS data were obtained confirming the stable adsorption of glucose and raffinose on an ultrafine pyrogenic silica surface modified by amino groups." @default.
- W2570206581 created "2017-01-13" @default.
- W2570206581 creator A5045217499 @default.
- W2570206581 date "1996-10-01" @default.
- W2570206581 modified "2023-09-26" @default.
- W2570206581 title "Temperature-Programmed Desorption Mass Spectrometry (TPDMS) of Dispersed Oxides" @default.
- W2570206581 cites W1990897197 @default.
- W2570206581 cites W2076142396 @default.
- W2570206581 cites W2171232605 @default.
- W2570206581 cites W4256475631 @default.
- W2570206581 doi "https://doi.org/10.1177/026361749601400505" @default.
- W2570206581 hasPublicationYear "1996" @default.
- W2570206581 type Work @default.
- W2570206581 sameAs 2570206581 @default.
- W2570206581 citedByCount "7" @default.
- W2570206581 crossrefType "journal-article" @default.
- W2570206581 hasAuthorship W2570206581A5045217499 @default.
- W2570206581 hasBestOaLocation W25702065811 @default.
- W2570206581 hasConcept C113196181 @default.
- W2570206581 hasConcept C121332964 @default.
- W2570206581 hasConcept C148898269 @default.
- W2570206581 hasConcept C150394285 @default.
- W2570206581 hasConcept C155916967 @default.
- W2570206581 hasConcept C160434732 @default.
- W2570206581 hasConcept C161790260 @default.
- W2570206581 hasConcept C162356407 @default.
- W2570206581 hasConcept C162711632 @default.
- W2570206581 hasConcept C178790620 @default.
- W2570206581 hasConcept C179104552 @default.
- W2570206581 hasConcept C185592680 @default.
- W2570206581 hasConcept C199033913 @default.
- W2570206581 hasConcept C2778839380 @default.
- W2570206581 hasConcept C2779851234 @default.
- W2570206581 hasConcept C43617362 @default.
- W2570206581 hasConcept C55493867 @default.
- W2570206581 hasConcept C62520636 @default.
- W2570206581 hasConcept C7070889 @default.
- W2570206581 hasConcept C93391505 @default.
- W2570206581 hasConceptScore W2570206581C113196181 @default.
- W2570206581 hasConceptScore W2570206581C121332964 @default.
- W2570206581 hasConceptScore W2570206581C148898269 @default.
- W2570206581 hasConceptScore W2570206581C150394285 @default.
- W2570206581 hasConceptScore W2570206581C155916967 @default.
- W2570206581 hasConceptScore W2570206581C160434732 @default.
- W2570206581 hasConceptScore W2570206581C161790260 @default.
- W2570206581 hasConceptScore W2570206581C162356407 @default.
- W2570206581 hasConceptScore W2570206581C162711632 @default.
- W2570206581 hasConceptScore W2570206581C178790620 @default.
- W2570206581 hasConceptScore W2570206581C179104552 @default.
- W2570206581 hasConceptScore W2570206581C185592680 @default.
- W2570206581 hasConceptScore W2570206581C199033913 @default.
- W2570206581 hasConceptScore W2570206581C2778839380 @default.
- W2570206581 hasConceptScore W2570206581C2779851234 @default.
- W2570206581 hasConceptScore W2570206581C43617362 @default.
- W2570206581 hasConceptScore W2570206581C55493867 @default.
- W2570206581 hasConceptScore W2570206581C62520636 @default.
- W2570206581 hasConceptScore W2570206581C7070889 @default.
- W2570206581 hasConceptScore W2570206581C93391505 @default.
- W2570206581 hasIssue "5" @default.
- W2570206581 hasLocation W25702065811 @default.
- W2570206581 hasOpenAccess W2570206581 @default.
- W2570206581 hasPrimaryLocation W25702065811 @default.
- W2570206581 hasRelatedWork W1975607095 @default.
- W2570206581 hasRelatedWork W1982450184 @default.
- W2570206581 hasRelatedWork W1999223662 @default.
- W2570206581 hasRelatedWork W2041795782 @default.
- W2570206581 hasRelatedWork W2056348120 @default.
- W2570206581 hasRelatedWork W2069987993 @default.
- W2570206581 hasRelatedWork W2077151206 @default.
- W2570206581 hasRelatedWork W2080477843 @default.
- W2570206581 hasRelatedWork W2082509176 @default.
- W2570206581 hasRelatedWork W2327711632 @default.
- W2570206581 hasVolume "14" @default.
- W2570206581 isParatext "false" @default.
- W2570206581 isRetracted "false" @default.
- W2570206581 magId "2570206581" @default.
- W2570206581 workType "article" @default.