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- W2570243542 abstract "Abstract This paper presents data for density ( ρ ) and relative viscosity ( η r ) measurements of aqueous solutions of thiamine hydrochloride, pyridoxine hydrochloride and sodium-L-ascorbate in dilute solutions (0–0.1) mol·kg−1 at three different temperatures, T = (275.15, 277.15 and 279.15) K and at 101.3 kPa. Density results have been used to calculate apparent molar volume of solute ( V ϕ ) , limiting apparent molar volume of solute ( V ϕ 0 ) , limiting apparent molar expansivity of solute ( E ϕ 0 ) , ( ∂ 2 V ϕ 0 / ∂ T 2 ) and coefficient of thermal expansion ( α ∗ ) . Calculated viscosity values have been correlated according to Jones-Dole equation to obtain Falkenhagen coefficient A, Jones-Dole viscosity B-coefficient, temperature derivative of B-coefficient i.e. ( d B / d T ) and hydration number ( n H ) . Free energy of activation for viscous flow per mole of solvent ( Δ μ 1 0 # ) , per mole of solute ( Δ μ 2 0 # ) , entropy of activation per mole of viscous flow of solution ( T Δ S 2 0 # ) and enthalpy of activation ( Δ H 2 0 # ) have also been computed through B-coefficient. These significant parameters have been discussed in terms of different molecular interactions." @default.
- W2570243542 created "2017-01-13" @default.
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- W2570243542 date "2017-04-01" @default.
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- W2570243542 title "Volumetric and viscometric study of thiamine hydrochloride, pyridoxine hydrochloride and sodium ascorbate at T=(275.15, 277.15 and 279.15)K in dilute aqueous solutions" @default.
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- W2570243542 doi "https://doi.org/10.1016/j.jct.2016.12.033" @default.
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