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- W2570663040 abstract "In the present study, the catalytic dehydration of ethanol to obtain ethylene over efficiently top-down modified zeolites L was investigated at temperature range of 100–300 °C. It revealed that the nature of an acidic Si(OH)Al groups determined the catalytic activity of the studied materials. The alkaline/acid treated zeolites L accommodating solely the isolated Si(OH)Al groups exhibited the highest catalytic activity and selectivity to ethylene. Modification routes increasing population of the hydrogen bonded Si(OH)Al⋯O species reduced an activity of the catalysts. The most active catalyst yielded 99% of ethanol conversion having 96% of ethylene yield at 280 °C. Upon the stability test for 30 h during the reaction, the modified zeolite L showed neither formation of higher hydrocarbons nor deactivation due to carbon deposition." @default.
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- W2570663040 date "2017-03-01" @default.
- W2570663040 modified "2023-10-14" @default.
- W2570663040 title "Alkaline-acid treated zeolite L as catalyst in ethanol dehydration process" @default.
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- W2570663040 doi "https://doi.org/10.1016/j.micromeso.2016.12.035" @default.
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