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• W2570861074 abstract "Porphyrin–polyyne [3]- and [5]rotaxanes have been synthesized by condensing aldehyde–rotaxanes with pyrrole or dipyrromethane. The crystal structure of a [3]rotaxane shows that the macrocycles adopt compact conformations, holding the hexaynes near the porphyrin core, and that the phenanthroline units form intermolecular π-stacked dimers in the solid. Fluorescence spectra reveal singlet excited-state energy transfer from the threaded hexayne to the porphyrin, from the phenanthroline to the porphyrin, and from the phenanthroline to the hexayne." @default.
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• W2570861074 date "2017-01-05" @default.
• W2570861074 modified "2023-10-15" @default.
• W2570861074 title "Porphyrin–Polyyne [3]- and [5]Rotaxanes" @default.
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• W2570861074 doi "https://doi.org/10.1021/acs.orglett.6b03528" @default.
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