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- W2570936164 abstract "On the basis of selected reagents and reaction conditions, a chiral dinuclear trapped-valence CoII/CoIII complex was conveniently obtained {[Co2(L)(O2CCH2CO2)(H2O)]·EtOH·1.25H2O, being H3L = 2-(5-bromo-2-hydroxyphenyl)-1,3-bis[4-(5-bromo-2-hydroxyphenyl)-3-azabut-3-enyl]-1,3-imidazolidine)}. This complex behaves as a compact amphiphile, whose hydrophilic pole attracts ethanol and water solvates. Its crystal packing shows a hierarchical structure controlled by an amphiphatic nature. Molecules of each enantiomer are head-to-tail connected through intermolecular hydrogen bonds to give rise to infinite helixes. These helical chains are stacked in homochiral two-dimensional sheets with hydrophilic pockets, where water and ethanol solvates are trapped. Each layer displays its homoenantiomeric helixes with a parallel orientation, while their mirror helixes, which are alternate, are antiparallelly oriented." @default.
- W2570936164 created "2017-01-13" @default.
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- W2570936164 date "2017-01-20" @default.
- W2570936164 modified "2023-10-18" @default.
- W2570936164 title "Hierarchical Assembly of Antiparallel Homochiral Sheets Formed by Hydrogen-Bonded Helixes of a Trapped-Valence Co<sup>II</sup>/Co<sup>III</sup> Complex" @default.
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- W2570936164 doi "https://doi.org/10.1021/acs.cgd.6b01269" @default.
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