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- W2571123923 abstract "Three ratio method of dissolved gases is a most recognized method to evaluate the insulation of oil-filled equipment, but it lacks the quantitative relation of dissolved gases and severity of the defects. This paper study the reaction mechanism of transformer oil pyrolysis based on molecular simulation. First, thermal analysis technique TG-DSC is used to observe the quality and energy changes during the process of transformer oil decomposition. Then, by using reactive reaction force field (ReaxFF), the three typical hydrocarbons in transformer oil-alkane, cycloalkane and aromatic is simulated in a liquid system and the microscopic decomposition mechanism of transformer oil is studied. Through the establishment of a liquid system consisting of three different kinds of hydrocarbons, and the minimization of energy balance system, the pyrolysis of them in NVT system is simulated under different temperatures. Then the relationship between temperature and the process of pyrolysis is concluded. This study reveals the pyrolysis dynamic mechanism of the transformer oil on the atomic level, corresponding to the real pyrolysis successfully." @default.
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- W2571123923 date "2016-09-01" @default.
- W2571123923 modified "2023-09-25" @default.
- W2571123923 title "Reaction mechanism of transformer oil pyrolysis based on ReaxFF molecular simulation" @default.
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- W2571123923 doi "https://doi.org/10.1109/ichve.2016.7800664" @default.
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