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- W2573938064 abstract "Based on the surface pre-melting model, accurate thermodynamic relations of the melting temperature of nanocrystals with different shapes (tetrahedron, cube, octahedron, dodecahedron, icosahedron, nanowire) were derived. The theoretically calculated melting temperatures are in relative good agreements with experimental, molecular dynamic simulation and other theoretical results for nanometer Au, Ag, Al, In and Pb. It is found that the particle size and shape have notable effects on the melting temperature of nanocrystals, and the smaller the particle size, the greater the effect of shape. Furthermore, at the same equivalent radius, the more the shape deviates from sphere, the lower the melting temperature is. The value of melting temperature depression of cylindrical nanowire is just half of that of spherical nanoparticle with an identical radius. The theoretical relations enable one to quantitatively describe the influence regularities of size and shape on the melting temperature and to provide an effective way to predict and interpret the melting temperature of nanocrystals with different sizes and shapes." @default.
- W2573938064 created "2017-01-26" @default.
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- W2573938064 date "2017-05-01" @default.
- W2573938064 modified "2023-10-10" @default.
- W2573938064 title "Accurate thermodynamic relations of the melting temperature of nanocrystals with different shapes and pure theoretical calculation" @default.
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- W2573938064 doi "https://doi.org/10.1016/j.matchemphys.2017.01.049" @default.
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