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- W2574005770 abstract "An efficient route to pharmacologically interesting isoindolinone-based α-amino phosphonates is described via asymmetric hydrophosphonylation of in situ generated ketimines catalyzed by BINOL-derived phosphoric acid. The reaction proceeds smoothly at ambient temperature affording a variety of α-amino phosphonates with a quaternary stereogenic center embedded in isoindolinone motif in high yields with excellent enantiomeric ratios (up to 98.5:1.5 er). Several interesting transformations of the products into valuable synthetic intermediates are also depicted." @default.
- W2574005770 created "2017-01-26" @default.
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- W2574005770 date "2017-01-11" @default.
- W2574005770 modified "2023-09-24" @default.
- W2574005770 title "Enantioselective Hydrophosphonylation of <i>in Situ</i> Generated <i>N</i>-Acyl Ketimines Catalyzed by BINOL-Derived Phosphoric Acid" @default.
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- W2574005770 doi "https://doi.org/10.1021/acs.orglett.6b03623" @default.
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