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- W2574136075 abstract "A simple and ubiquitous nickel(II) complex NiCl2(PPh3)2 catalyzes polymerization of oligothiophenes. Treatment of chlorobithiophene with chloromagnesium 2,2,6,6-tetramethylpiperidin-1-yl lithium chloride salt (TMPMgCl·LiCl) followed by addition of 2.0 mol % NiCl2(PPh3)2 undergoes deprotonative polymerization leading to poly(3-hexylthiophene) (P3HT) with Mn = 13000 and Mw/Mn = 1.67 (74% yield). The related terthiophene and quaterthiophene also polymerize to afford the corresponding polythiophene while little polymerization takes place with 2-chloro-3-hexylthiophene under similar conditions." @default.
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- W2574136075 date "2017-04-05" @default.
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- W2574136075 title "Remarkable Reactivity Differences of Chlorothiophene and Chlorinated Oligothiophenes in NiCl<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub>-catalyzed Polymerization" @default.
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- W2574136075 doi "https://doi.org/10.1246/cl.161180" @default.
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