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- W2575149871 abstract "Abstract To improve the film-forming property and gas permeability of poly(ionic liquid) membranes, a series of semi-interpenetrating polymer network (semi-IPN) membranes were successfully synthesized by incorporating linear polyvinyl acetate (PVAc) into a cross-linked poly (ionic liquid) ( c -PIL) network. The resultant PVAc/c-PIL semi-IPN membranes exhibited good film-forming property and various phase separation morphologies, from spherical, interconnected to co-continuous microstructure. Also, the formation of semi-IPN structure endowed the membrane with an improved mechanical properties and slightly depressed glass transition temperatures. From gas permeation measurement results, PVAc/c-PIL semi-IPN membranes demonstrated gradually higher CO 2 permeability coefficient with the increase of c -PIL content, while CO 2 /N 2 permselectivity increased initially and then decreased slightly. The best permeability and permselectivity of the membrane reached 36.1 Barrer and 59.6, respectively, when the c -PIL content was 50 wt%, which approached to the 2008 Robeson limit. Moreover, the permeability of CO 2 in PVAc/c-PIL-50 semi-IPN membrane increased with increasing temperature across their glass transition temperatures, while the permselectivity of CO 2 /N 2 decreased." @default.
- W2575149871 created "2017-01-26" @default.
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- W2575149871 date "2017-04-01" @default.
- W2575149871 modified "2023-10-17" @default.
- W2575149871 title "Synthesis and gas transport properties of poly(ionic liquid) based semi-interpenetrating polymer network membranes for CO2/N2 separation" @default.
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- W2575149871 doi "https://doi.org/10.1016/j.memsci.2017.01.022" @default.
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