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• W2575313596 abstract "Abstract The non-edible Sapindus mukurossi oil, containing more than 80% unsaturated fatty acids, has potential applications in plastics manufacturing. In this research, a green and economically attractive chemo-enzymatic production of epoxidized fatty acids was performed in the presence of lipase Candida sp. 99–125 and H 2 O 2 in different systems. The obtained experimental results demonstrated that the solvent-free and n -hexane systems yielded superior results compared to other organic solvent systems. A molecular dynamic simulation further proved the influence of different solvents on the structure of lipase. Maximization of the key parameters including enzyme loading, reaction time, molar ratio of H 2 O 2 to the number of double bonds in the substrate, agitation speed, H 2 O 2 addition frequency, and temperature were performed in a solvent-free system. The oxirane value reached 4.61% in 8 h under a gradient temperature profile (first incubated at 30 °C for 6 h, then increased to 35 °C and maintained for another 2 h) with continuous addition of H 2 O 2 . The total molar amount of H 2 O 2 added was equal to the number of C C bonds in the substrate (expressed in moles)." @default.
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• W2575313596 date "2017-04-01" @default.
• W2575313596 modified "2023-10-12" @default.
• W2575313596 title "Chemo-enzymatic epoxidation of Sapindus mukurossi fatty acids catalyzed with Candida sp. 99–125 lipase in a solvent-free system" @default.
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• W2575313596 doi "https://doi.org/10.1016/j.indcrop.2017.01.013" @default.
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