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- W2576317660 abstract "Effective electrocatalysts for the hydrogen evolution reaction (HER) in alkaline electrolytes can be developed via a simple solvothermal process. In this work, first, the prepared CoMoS nanomaterials through solvothermal treatment have a porous, defect-rich, and vertically aligned nanostructure, which is beneficial for the HER in an alkaline medium. Second, electron transfer from cobalt to MoS2 that reduces the unoccupied d orbitals of molybdenum can also enhance the HER kinetics in an alkaline medium. This has been demonstrated via a comparison of the catalytic performances of CoMoS, CoS, and MoS2. Third, the solvothermal treatment time evidently impacts the electrocatalytic activity. As a result, after 24 h of solvothermal treatment, the prepared CoMoS nanomaterials exhibit the lowest onset potential (42 mV) and overpotential (98 mV) for delivering a current density of 10 mA cm-2 in a 1 M KOH solution. Thus, this study provides a simple method to prepare efficient electrocatalysts for the HER in an alkaline medium." @default.
- W2576317660 created "2017-01-26" @default.
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- W2576317660 date "2017-01-31" @default.
- W2576317660 modified "2023-09-30" @default.
- W2576317660 title "Hierarchically Porous Electrocatalyst with Vertically Aligned Defect-Rich CoMoS Nanosheets for the Hydrogen Evolution Reaction in an Alkaline Medium" @default.
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- W2576317660 doi "https://doi.org/10.1021/acsami.6b15244" @default.
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