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- W2576567830 abstract "Abstract The ruthenium(II) complex cis-[RuCl 2 (PPh 3 ) 2 (L1)] ( 1 ) where L1 = 2-(2’-pyridyl)quinoline was obtained in high yield from the reaction of [RuCl 2 (PPh 3 ) 3 ] with L1. The new compound was characterized by different spectroscopic methods including FT-IR, UV-Vis, NMR ( 1 H, 31 P) spectroscopy along with a mass spectrometric analysis (ESI-MS) and conductivity measurements. 31 P NMR spectroscopy provided evidence that the two PPh 3 ligands are orientated trans to each other in an octahedral environment. Complex ( 1 ) was tested in the transfer hydrogenation of various ketones in 2-propanol at 82 o C. The catalytic activity of ( 1 ) displayed quantitative conversions for benzophenone and 4-chloroacetophenone." @default.
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- W2576567830 date "2016-01-01" @default.
- W2576567830 modified "2023-09-23" @default.
- W2576567830 title "A 2-(2’-pyridyl)quinoline ruthenium(II) complex as an active catalyst for the transfer hydrogenation of ketones" @default.
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- W2576567830 doi "https://doi.org/10.1515/chem-2016-0034" @default.
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