Matches in SemOpenAlex for { <https://semopenalex.org/work/W2577553721> ?p ?o ?g. }
- W2577553721 endingPage "1877" @default.
- W2577553721 startingPage "1871" @default.
- W2577553721 abstract "Clusters with filled electronic shells and a large gap between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) are generally energetically and chemically stable. Enabling clusters to become electron donors with low ionization energies or electron acceptors with high electron affinities usually requires changing the valence electron count. Here we demonstrate that a metal cluster may be transformed from an electron donor to an acceptor by exchanging ligands while the neutral form of the clusters has closed electronic shells. Our studies on Co6Te8(PEt3)m(CO)n (m + n = 6) clusters show that Co6Te8(PEt3)6 has a closed electronic shell and a low ionization energy of 4.74 eV, and the successive replacement of PEt3 by CO ligands ends with Co6Te8(CO)6 exhibiting halogen-like behavior. Both the low ionization energy Co6Te8(PEt3)6 and high electron affinity Co6Te8(CO)6 have closed electronic shells marked by high HOMO-LUMO gaps of 1.24 and 1.39 eV, respectively. Further, the clusters with an even number of ligands favor a symmetrical placement of ligands around the metal core." @default.
- W2577553721 created "2017-01-26" @default.
- W2577553721 creator A5044101855 @default.
- W2577553721 creator A5048761573 @default.
- W2577553721 creator A5077966833 @default.
- W2577553721 date "2017-01-26" @default.
- W2577553721 modified "2023-10-17" @default.
- W2577553721 title "Metal Chalcogenide Clusters with Closed Electronic Shells and the Electronic Properties of Alkalis and Halogens" @default.
- W2577553721 cites W179471644 @default.
- W2577553721 cites W1885600419 @default.
- W2577553721 cites W1965114562 @default.
- W2577553721 cites W1974170974 @default.
- W2577553721 cites W1981368803 @default.
- W2577553721 cites W1984365843 @default.
- W2577553721 cites W1985024475 @default.
- W2577553721 cites W2003527277 @default.
- W2577553721 cites W2012911367 @default.
- W2577553721 cites W2013013090 @default.
- W2577553721 cites W2020830441 @default.
- W2577553721 cites W2026992473 @default.
- W2577553721 cites W2030675984 @default.
- W2577553721 cites W2031026846 @default.
- W2577553721 cites W2031686744 @default.
- W2577553721 cites W2033699021 @default.
- W2577553721 cites W2036327914 @default.
- W2577553721 cites W2037244776 @default.
- W2577553721 cites W2038568105 @default.
- W2577553721 cites W2046043826 @default.
- W2577553721 cites W2047616133 @default.
- W2577553721 cites W2052556091 @default.
- W2577553721 cites W2055770627 @default.
- W2577553721 cites W2056319595 @default.
- W2577553721 cites W2063964483 @default.
- W2577553721 cites W2066286007 @default.
- W2577553721 cites W2067352086 @default.
- W2577553721 cites W2069468471 @default.
- W2577553721 cites W2070779586 @default.
- W2577553721 cites W2072594364 @default.
- W2577553721 cites W2076483678 @default.
- W2577553721 cites W2077702579 @default.
- W2577553721 cites W2078448353 @default.
- W2577553721 cites W2090812470 @default.
- W2577553721 cites W2092398097 @default.
- W2577553721 cites W2108299472 @default.
- W2577553721 cites W2134463853 @default.
- W2577553721 cites W2140537016 @default.
- W2577553721 cites W2150345533 @default.
- W2577553721 cites W2153258495 @default.
- W2577553721 cites W2242193728 @default.
- W2577553721 cites W2256176966 @default.
- W2577553721 cites W2268929617 @default.
- W2577553721 cites W2271711553 @default.
- W2577553721 cites W2315022957 @default.
- W2577553721 cites W2326741576 @default.
- W2577553721 cites W2330777009 @default.
- W2577553721 cites W2331035849 @default.
- W2577553721 cites W2338015967 @default.
- W2577553721 cites W2470439878 @default.
- W2577553721 cites W2501442783 @default.
- W2577553721 doi "https://doi.org/10.1021/jacs.6b09416" @default.
- W2577553721 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28081603" @default.
- W2577553721 hasPublicationYear "2017" @default.
- W2577553721 type Work @default.
- W2577553721 sameAs 2577553721 @default.
- W2577553721 citedByCount "49" @default.
- W2577553721 countsByYear W25775537212017 @default.
- W2577553721 countsByYear W25775537212018 @default.
- W2577553721 countsByYear W25775537212019 @default.
- W2577553721 countsByYear W25775537212020 @default.
- W2577553721 countsByYear W25775537212021 @default.
- W2577553721 countsByYear W25775537212022 @default.
- W2577553721 countsByYear W25775537212023 @default.
- W2577553721 crossrefType "journal-article" @default.
- W2577553721 hasAuthorship W2577553721A5044101855 @default.
- W2577553721 hasAuthorship W2577553721A5048761573 @default.
- W2577553721 hasAuthorship W2577553721A5077966833 @default.
- W2577553721 hasBestOaLocation W25775537212 @default.
- W2577553721 hasConcept C121332964 @default.
- W2577553721 hasConcept C14158195 @default.
- W2577553721 hasConcept C145148216 @default.
- W2577553721 hasConcept C147120987 @default.
- W2577553721 hasConcept C147192597 @default.
- W2577553721 hasConcept C147597530 @default.
- W2577553721 hasConcept C164866538 @default.
- W2577553721 hasConcept C168900304 @default.
- W2577553721 hasConcept C178790620 @default.
- W2577553721 hasConcept C184779094 @default.
- W2577553721 hasConcept C185592680 @default.
- W2577553721 hasConcept C198291218 @default.
- W2577553721 hasConcept C199360897 @default.
- W2577553721 hasConcept C2778177714 @default.
- W2577553721 hasConcept C2780263894 @default.
- W2577553721 hasConcept C2781238429 @default.
- W2577553721 hasConcept C2900893 @default.
- W2577553721 hasConcept C32909587 @default.
- W2577553721 hasConcept C37649677 @default.
- W2577553721 hasConcept C38649801 @default.
- W2577553721 hasConcept C41008148 @default.