FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2577573764> ?p ?o ?g. }

• W2577573764 endingPage "261" @default.
• W2577573764 startingPage "252" @default.
• W2577573764 abstract "Two novel ferrocene organometallic complexes of [Mn(C16H16FeN2O2)4(H2O)2]Cl2 1 and [Co(C16H16FeN2O2)4(H2O)2](NO3)2·3H2O 2 were synthesized under solvothermal conditions and characterized by IR spectroscopy, elemental analyses, and thermogravimetric analyses. Single-crystal X-ray diffraction analyses revealed that the two complexes were centrosymmetric species with the central atom in six-coordinated environment. Interestingly, supramolecular constructions of 1 and 2 are totally different due to intriguing hydrogen-bonded systems. Complex 1 was dominated by non-classical CH⋯O hydrogen bonds while 2 was assembled by both classical OH⋯O hydrogen bonds and CH⋯O hydrogen bonds. Different from chloride ions only balanced the electric charge in 1, nitrate anions in 2 not only balanced the electric charge but also contributed largely to stability through OH⋯O hydrogen bonds. Electrochemical investigation revealed that both 1 (ΔEp = 189 mV, Ipa/Ipc = 1.32) and 2 (ΔEp = 95 mV, Ipa/Ipc = 0.96) displayed anticipated one-electron redox process of the ferrocenyl group. Moreover, complex 2 had better redox reversibility than 1. Furthermore, UV–Vis absorption spectrum has been applied to prove the stability of complex ions of [Mn(C16H16FeN2O2)4(H2O)2]2+ and [Co(C16H16FeN2O2)4(H2O)2]2+ in acetonitrile for better understanding of electrochemical investigation. It’s significant to reveal the structural and electrochemical characters of these kind of ferrocene-containing complexes for the further application on areas of anticancer metallodrugs based on their good redox-activity." @default.
• W2577573764 created "2017-01-26" @default.
• W2577573764 creator A5015627834 @default.
• W2577573764 creator A5056904739 @default.
• W2577573764 creator A5086624514 @default.
• W2577573764 date "2017-04-01" @default.
• W2577573764 modified "2023-09-25" @default.
• W2577573764 title "Mn(II) and Co(II) complexes functionalized by imidazolyl-ferrocene: Electrochemical property and different supramolecular architectures driven by intriguing hydrogen-bonded system" @default.
• W2577573764 cites W1808538967 @default.
• W2577573764 cites W1941982675 @default.
• W2577573764 cites W1961936696 @default.
• W2577573764 cites W1964277385 @default.
• W2577573764 cites W1964299877 @default.
• W2577573764 cites W1969792769 @default.
• W2577573764 cites W1972296763 @default.
• W2577573764 cites W1973759734 @default.
• W2577573764 cites W1981594681 @default.
• W2577573764 cites W1986329902 @default.
• W2577573764 cites W1988872452 @default.
• W2577573764 cites W1990048466 @default.
• W2577573764 cites W1990283963 @default.
• W2577573764 cites W2002085720 @default.
• W2577573764 cites W2008270149 @default.
• W2577573764 cites W2018311893 @default.
• W2577573764 cites W2020099575 @default.
• W2577573764 cites W2024882009 @default.
• W2577573764 cites W2037568310 @default.
• W2577573764 cites W2040010866 @default.
• W2577573764 cites W2041701642 @default.
• W2577573764 cites W2050980700 @default.
• W2577573764 cites W2054960963 @default.
• W2577573764 cites W2057814482 @default.
• W2577573764 cites W2059287912 @default.
• W2577573764 cites W2065340378 @default.
• W2577573764 cites W2081965503 @default.
• W2577573764 cites W2103020936 @default.
• W2577573764 cites W2139187462 @default.
• W2577573764 cites W2148003304 @default.
• W2577573764 cites W2168377988 @default.
• W2577573764 cites W2171096596 @default.
• W2577573764 cites W2185858071 @default.
• W2577573764 cites W2203995762 @default.
• W2577573764 cites W2309508791 @default.
• W2577573764 cites W2330674653 @default.
• W2577573764 cites W2382532213 @default.
• W2577573764 cites W2403681610 @default.
• W2577573764 cites W2432902241 @default.
• W2577573764 cites W746912768 @default.
• W2577573764 doi "https://doi.org/10.1016/j.poly.2017.01.016" @default.
• W2577573764 hasPublicationYear "2017" @default.
• W2577573764 type Work @default.
• W2577573764 sameAs 2577573764 @default.
• W2577573764 citedByCount "8" @default.
• W2577573764 countsByYear W25775737642017 @default.
• W2577573764 countsByYear W25775737642018 @default.
• W2577573764 countsByYear W25775737642019 @default.
• W2577573764 countsByYear W25775737642020 @default.
• W2577573764 crossrefType "journal-article" @default.
• W2577573764 hasAuthorship W2577573764A5015627834 @default.
• W2577573764 hasAuthorship W2577573764A5056904739 @default.
• W2577573764 hasAuthorship W2577573764A5086624514 @default.
• W2577573764 hasConcept C112887158 @default.
• W2577573764 hasConcept C115624301 @default.
• W2577573764 hasConcept C147789679 @default.
• W2577573764 hasConcept C17525397 @default.
• W2577573764 hasConcept C178790620 @default.
• W2577573764 hasConcept C179104552 @default.
• W2577573764 hasConcept C185592680 @default.
• W2577573764 hasConcept C192406513 @default.
• W2577573764 hasConcept C2777237805 @default.
• W2577573764 hasConcept C2777463227 @default.
• W2577573764 hasConcept C32909587 @default.
• W2577573764 hasConcept C52859227 @default.
• W2577573764 hasConcept C55904794 @default.
• W2577573764 hasConcept C8010536 @default.
• W2577573764 hasConcept C93275456 @default.
• W2577573764 hasConceptScore W2577573764C112887158 @default.
• W2577573764 hasConceptScore W2577573764C115624301 @default.
• W2577573764 hasConceptScore W2577573764C147789679 @default.
• W2577573764 hasConceptScore W2577573764C17525397 @default.
• W2577573764 hasConceptScore W2577573764C178790620 @default.
• W2577573764 hasConceptScore W2577573764C179104552 @default.
• W2577573764 hasConceptScore W2577573764C185592680 @default.
• W2577573764 hasConceptScore W2577573764C192406513 @default.
• W2577573764 hasConceptScore W2577573764C2777237805 @default.
• W2577573764 hasConceptScore W2577573764C2777463227 @default.
• W2577573764 hasConceptScore W2577573764C32909587 @default.
• W2577573764 hasConceptScore W2577573764C52859227 @default.
• W2577573764 hasConceptScore W2577573764C55904794 @default.
• W2577573764 hasConceptScore W2577573764C8010536 @default.
• W2577573764 hasConceptScore W2577573764C93275456 @default.
• W2577573764 hasLocation W25775737641 @default.
• W2577573764 hasOpenAccess W2577573764 @default.
• W2577573764 hasPrimaryLocation W25775737641 @default.
• W2577573764 hasRelatedWork W1491053291 @default.
• W2577573764 hasRelatedWork W1987674700 @default.
• W2577573764 hasRelatedWork W2002273097 @default.
• W2577573764 hasRelatedWork W2012675768 @default.

• next