FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2577741653> ?p ?o ?g. }

• W2577741653 endingPage "561" @default.
• W2577741653 startingPage "552" @default.
• W2577741653 abstract "Abstract In this work electrogenerated active chlorine was used to treat fluoroquinolones, a class of antibiotics that is highly consumed and frequently found in waste and natural waters. Taking into account the structural variety and diverse molecular forms of these pharmaceuticals, their structure-reactivity relationship toward active chlorine was studied. Three representative fluoroquinolones: ciprofloxacin, norfloxacin and levofloxacin were considered. Despite structural differences, the primary by-products evidenced that the major reactive part of fluoroquinolones was the piperazyl ring. However, ciprofloxacin and norfloxacin were degraded faster than levofloxacin, due to the fact that secondary amines on ciprofloxacin and norfloxacin were more reactive toward active chlorine than tertiary amines on levofloxacin. The reactivity of cationic and neutral forms of the fluoroquinolones was also evaluated using both experimental and theoretical procedures. Experimental results evidenced that the neutral forms have higher degradation rates than the cationic structures. Theoretical analysis of net charge on atoms (obtained by the natural bonding orbitals method) indicated that the reactive moieties on the neutral form of antibiotics have a high nucleophilicity. Therefore, this form is more susceptible to electrophilic attacks by chlorine species than the cationic one. Additionally, the environmental impact was evaluated considering the evolution of antimicrobial activity and its correlation with the antibiotics transformations. Finally, simulated hospital wastewater containing norfloxacin was treated. The electrogenerated active chlorine removed 100% of the antimicrobial activity in a short period (40 min), indicating that this system is an interesting option for treating hospital wastewaters and decreasing the negative environmental impact of the input of fluoroquinolones into natural media." @default.
• W2577741653 created "2017-01-26" @default.
• W2577741653 creator A5006403757 @default.
• W2577741653 creator A5044320845 @default.
• W2577741653 creator A5045212067 @default.
• W2577741653 creator A5082061747 @default.
• W2577741653 creator A5089137216 @default.
• W2577741653 date "2017-05-01" @default.
• W2577741653 modified "2023-09-27" @default.
• W2577741653 title "Structure-reactivity relationship in the degradation of three representative fluoroquinolone antibiotics in water by electrogenerated active chlorine" @default.
• W2577741653 cites W1966138471 @default.
• W2577741653 cites W1979719471 @default.
• W2577741653 cites W1980543898 @default.
• W2577741653 cites W1982535868 @default.
• W2577741653 cites W1982607879 @default.
• W2577741653 cites W1997151511 @default.
• W2577741653 cites W2000059268 @default.
• W2577741653 cites W2001700734 @default.
• W2577741653 cites W2009125083 @default.
• W2577741653 cites W2009989575 @default.
• W2577741653 cites W2015774781 @default.
• W2577741653 cites W2022564688 @default.
• W2577741653 cites W2031223726 @default.
• W2577741653 cites W2031705310 @default.
• W2577741653 cites W2034712982 @default.
• W2577741653 cites W2038144504 @default.
• W2577741653 cites W2050647557 @default.
• W2577741653 cites W2058010120 @default.
• W2577741653 cites W2061692717 @default.
• W2577741653 cites W2068448179 @default.
• W2577741653 cites W2069700993 @default.
• W2577741653 cites W2071577741 @default.
• W2577741653 cites W2074502234 @default.
• W2577741653 cites W2080824589 @default.
• W2577741653 cites W2085525548 @default.
• W2577741653 cites W2086679295 @default.
• W2577741653 cites W2090139308 @default.
• W2577741653 cites W2094793806 @default.
• W2577741653 cites W2099650842 @default.
• W2577741653 cites W2128513781 @default.
• W2577741653 cites W2142102316 @default.
• W2577741653 cites W2177618667 @default.
• W2577741653 cites W2229264511 @default.
• W2577741653 cites W2288299498 @default.
• W2577741653 cites W2307591848 @default.
• W2577741653 cites W2329136011 @default.
• W2577741653 cites W2415473024 @default.
• W2577741653 cites W2494304046 @default.
• W2577741653 cites W2508930034 @default.
• W2577741653 cites W2528638597 @default.
• W2577741653 cites W4256603424 @default.
• W2577741653 cites W793789966 @default.
• W2577741653 cites W883125052 @default.
• W2577741653 doi "https://doi.org/10.1016/j.cej.2017.01.062" @default.
• W2577741653 hasPublicationYear "2017" @default.
• W2577741653 type Work @default.
• W2577741653 sameAs 2577741653 @default.
• W2577741653 citedByCount "50" @default.
• W2577741653 countsByYear W25777416532017 @default.
• W2577741653 countsByYear W25777416532018 @default.
• W2577741653 countsByYear W25777416532019 @default.
• W2577741653 countsByYear W25777416532020 @default.
• W2577741653 countsByYear W25777416532021 @default.
• W2577741653 countsByYear W25777416532022 @default.
• W2577741653 countsByYear W25777416532023 @default.
• W2577741653 crossrefType "journal-article" @default.
• W2577741653 hasAuthorship W2577741653A5006403757 @default.
• W2577741653 hasAuthorship W2577741653A5044320845 @default.
• W2577741653 hasAuthorship W2577741653A5045212067 @default.
• W2577741653 hasAuthorship W2577741653A5082061747 @default.
• W2577741653 hasAuthorship W2577741653A5089137216 @default.
• W2577741653 hasConcept C107872376 @default.
• W2577741653 hasConcept C142724271 @default.
• W2577741653 hasConcept C178790620 @default.
• W2577741653 hasConcept C185592680 @default.
• W2577741653 hasConcept C204787440 @default.
• W2577741653 hasConcept C2776910235 @default.
• W2577741653 hasConcept C2779679103 @default.
• W2577741653 hasConcept C41008148 @default.
• W2577741653 hasConcept C501593827 @default.
• W2577741653 hasConcept C505241676 @default.
• W2577741653 hasConcept C55493867 @default.
• W2577741653 hasConcept C71924100 @default.
• W2577741653 hasConcept C76155785 @default.
• W2577741653 hasConceptScore W2577741653C107872376 @default.
• W2577741653 hasConceptScore W2577741653C142724271 @default.
• W2577741653 hasConceptScore W2577741653C178790620 @default.
• W2577741653 hasConceptScore W2577741653C185592680 @default.
• W2577741653 hasConceptScore W2577741653C204787440 @default.
• W2577741653 hasConceptScore W2577741653C2776910235 @default.
• W2577741653 hasConceptScore W2577741653C2779679103 @default.
• W2577741653 hasConceptScore W2577741653C41008148 @default.
• W2577741653 hasConceptScore W2577741653C501593827 @default.
• W2577741653 hasConceptScore W2577741653C505241676 @default.
• W2577741653 hasConceptScore W2577741653C55493867 @default.
• W2577741653 hasConceptScore W2577741653C71924100 @default.
• W2577741653 hasConceptScore W2577741653C76155785 @default.
• W2577741653 hasLocation W25777416531 @default.

• next