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- W2578132654 abstract "Epitaxial chromium ferrite (Fe 2 CrO 4 ), prepared by state‐of‐the‐art oxygen plasma assisted molecular beam epitaxy, is shown to exhibit unusual electronic transport properties driven by the crystallographic structure and composition of the material. Replacing 1/3 of the Fe cations with Cr converts the host ferrimagnet from a metal into a semiconductor by virtue of its fixed valence (3+); Cr substitutes for Fe at B sites in the spinel lattice. By contrast, replacing 2/3 of the Fe cations with Cr results in an insulator. Three candidate conductive paths, all involving electron hopping between Fe 2+ and Fe 3+ , are identified in Fe 2 CrO 4 . Moreover, Fe 2 CrO 4 is shown to be photoconductive across the visible portion of the electromagnetic spectrum. As a result, this material is of potential interest for important photo‐electrochemical processes such as water splitting." @default.
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- W2578132654 date "2017-01-13" @default.
- W2578132654 modified "2023-10-14" @default.
- W2578132654 title "Electronic and Optical Properties of a Semiconducting Spinel (Fe <sub>2</sub> CrO <sub>4</sub> )" @default.
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- W2578132654 doi "https://doi.org/10.1002/adfm.201605040" @default.
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