Matches in SemOpenAlex for { <https://semopenalex.org/work/W2578163721> ?p ?o ?g. }
Showing items 1 to 73 of
73
with 100 items per page.
- W2578163721 abstract "taining the calorimetric vessel and syringe with a long needle, evacuated and filled with Ar of special purity, the vessel was filled with the syringe, hermetically sealed, and transferred from the box to the measuring thermostat of the microcalorimeter which had been previously heated for I-2 h at the given temperature. The volume of the reaction solution in the vessel was 1.2 ml, and the weighed portion of the monomeric salt was 0.5-1.0 g. Polymerization did not take place after equilibrium was established (5 min) (verified on model samples using an efficient inhibitor, the stable iminoxyl radical, and also with the data from calibration of the instrument). The intrinsic viscosity of the polymers formed [~] was determined. The measurements were made in a 1N aqueous solution of NaCI at 30~ and then the viscosity-averag e molecular weight ~ was calculated with the equation ~ = 1.1210 -~ M ~ [5]. The degree of conversion of the monomer into a polymer was determined with calibration curves plotted with the PMR data (Varian T-60 NMR spectrometer) for model solutions, mixtures of monomer and polymer of different composition. With a 5.10-~-5.10 -~ mole/liter concentration of APS, a one-half order of the initial rate of polymerization with respect to the concentration of initiator was rigorously observed. The heat of polymerization was equal to 65.1 kJ/mole on conversion to one double bond of the monomer molecule." @default.
- W2578163721 created "2017-01-26" @default.
- W2578163721 creator A5018606382 @default.
- W2578163721 creator A5050029371 @default.
- W2578163721 creator A5072757883 @default.
- W2578163721 creator A5077148414 @default.
- W2578163721 creator A5085456749 @default.
- W2578163721 date "1988-01-01" @default.
- W2578163721 modified "2023-09-24" @default.
- W2578163721 title "KINETICS OF DEEP POLYMERIZATION OF DIMETHYLDIALLYLAMMONIUM CHLORIDE" @default.
- W2578163721 hasPublicationYear "1988" @default.
- W2578163721 type Work @default.
- W2578163721 sameAs 2578163721 @default.
- W2578163721 citedByCount "0" @default.
- W2578163721 crossrefType "journal-article" @default.
- W2578163721 hasAuthorship W2578163721A5018606382 @default.
- W2578163721 hasAuthorship W2578163721A5050029371 @default.
- W2578163721 hasAuthorship W2578163721A5072757883 @default.
- W2578163721 hasAuthorship W2578163721A5077148414 @default.
- W2578163721 hasAuthorship W2578163721A5085456749 @default.
- W2578163721 hasConcept C113196181 @default.
- W2578163721 hasConcept C121332964 @default.
- W2578163721 hasConcept C147789679 @default.
- W2578163721 hasConcept C148898269 @default.
- W2578163721 hasConcept C166940927 @default.
- W2578163721 hasConcept C178790620 @default.
- W2578163721 hasConcept C184651966 @default.
- W2578163721 hasConcept C185592680 @default.
- W2578163721 hasConcept C188027245 @default.
- W2578163721 hasConcept C2778695967 @default.
- W2578163721 hasConcept C44228677 @default.
- W2578163721 hasConcept C521977710 @default.
- W2578163721 hasConcept C62520636 @default.
- W2578163721 hasConceptScore W2578163721C113196181 @default.
- W2578163721 hasConceptScore W2578163721C121332964 @default.
- W2578163721 hasConceptScore W2578163721C147789679 @default.
- W2578163721 hasConceptScore W2578163721C148898269 @default.
- W2578163721 hasConceptScore W2578163721C166940927 @default.
- W2578163721 hasConceptScore W2578163721C178790620 @default.
- W2578163721 hasConceptScore W2578163721C184651966 @default.
- W2578163721 hasConceptScore W2578163721C185592680 @default.
- W2578163721 hasConceptScore W2578163721C188027245 @default.
- W2578163721 hasConceptScore W2578163721C2778695967 @default.
- W2578163721 hasConceptScore W2578163721C44228677 @default.
- W2578163721 hasConceptScore W2578163721C521977710 @default.
- W2578163721 hasConceptScore W2578163721C62520636 @default.
- W2578163721 hasLocation W25781637211 @default.
- W2578163721 hasOpenAccess W2578163721 @default.
- W2578163721 hasPrimaryLocation W25781637211 @default.
- W2578163721 hasRelatedWork W1579551296 @default.
- W2578163721 hasRelatedWork W1971044723 @default.
- W2578163721 hasRelatedWork W1974852521 @default.
- W2578163721 hasRelatedWork W1980413027 @default.
- W2578163721 hasRelatedWork W2008893473 @default.
- W2578163721 hasRelatedWork W2038717057 @default.
- W2578163721 hasRelatedWork W2047502505 @default.
- W2578163721 hasRelatedWork W2049214937 @default.
- W2578163721 hasRelatedWork W2059497140 @default.
- W2578163721 hasRelatedWork W2062254976 @default.
- W2578163721 hasRelatedWork W2112791481 @default.
- W2578163721 hasRelatedWork W2115259990 @default.
- W2578163721 hasRelatedWork W2151330703 @default.
- W2578163721 hasRelatedWork W2383044619 @default.
- W2578163721 hasRelatedWork W2393305949 @default.
- W2578163721 hasRelatedWork W2561661936 @default.
- W2578163721 hasRelatedWork W855920154 @default.
- W2578163721 hasRelatedWork W2182483361 @default.
- W2578163721 hasRelatedWork W2522705515 @default.
- W2578163721 hasRelatedWork W2861547101 @default.
- W2578163721 isParatext "false" @default.
- W2578163721 isRetracted "false" @default.
- W2578163721 magId "2578163721" @default.
- W2578163721 workType "article" @default.