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• W2578654162 abstract "Asymmetric Mannich-type reaction employing 5-isopropyl-3-phenyl-2-thioxoimidazolidin-4-one as a chiral auxiliary with various aldimines to obtain enantiomerically enriched β-amino carbonyl functionalities with good yields and high trans-diastereoselectivities has been described. In order to establish the stereochemical outcome of the reaction, the Mannich-adduct was hydrolysed using LiOH/H2O2 and subsequently cyclized with thionyl chloride to afford the corresponding β-lactam in good yield and high stereoselectivity." @default.
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• W2578654162 date "2017-01-13" @default.
• W2578654162 modified "2023-09-27" @default.
• W2578654162 title "An Auxiliary-Mediated Alkylation Approach Towards the Synthesis of β-Amino Carbonyl Derivatives" @default.
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• W2578654162 doi "https://doi.org/10.1002/slct.201601486" @default.
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