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- W25797427 abstract "CO oxidation over YBa2Cu3−δMeδO6+x, where Me is Co or Al, has been studied. The activity for CO oxidation decreases with increasing degree of substitution in the B site, in the case of substitution both with a more active element (Co) and with an inactive element (Al). The active site is believed to consist of -Cu-()-Cu-, where () can be an oxygen species O or an oxygen vacancy []. Dilution of this site with less active-Cu-()-Me-results in a lower activity. Nitrogen-annealed samples show a considerably higher activity than oxygen-annealed samples. Oxidation-reduction experiments suggest that bulk influences such as oxygen diffusion and filling of vacancies also affect activity." @default.
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- W25797427 date "1992-12-01" @default.
- W25797427 modified "2023-09-26" @default.
- W25797427 title "Oxidation of carbon monoxide over cobalt and aluminium substituted Y$z.sbnd;Ba$z.sbnd;Cu$z.sbnd;O perovskites" @default.
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- W25797427 doi "https://doi.org/10.1016/0021-9517(92)90307-4" @default.
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