Matches in SemOpenAlex for { <https://semopenalex.org/work/W2580457814> ?p ?o ?g. }
- W2580457814 endingPage "28" @default.
- W2580457814 startingPage "1" @default.
- W2580457814 abstract "Tremendous progress has been made in the construction of oligosaccharides, and many impressive examples of large and complex oligosaccharide total syntheses have appeared over the years. The stability, lifetime, and reactivity of an oxocarbenium ion depend besides the nature of the counterion on the nature and orientation of the functional groups present on the carbohydrate ring. This chapter explores the role of oxocarbenium ions and contact or close ion pairs (CIPs) that features a glycosyl cation, in chemical glycosylation reactions. It deals with the stability, reactivity, and -conformational behavior of glycosyl oxocarbenium ions, and describes their intermediacy in the assembly of (complex) oligosaccharides. The chapter presents sophisticated and detailed DFT computational approaches to study glycosyl oxocarbenium ions. Where many anomeric triflates have been spectroscopically characterized, glycosyl oxocarbenium ions are too reactive to detect by straightforward NMR techniques. NMR spectroscopy has been used to characterize a multitude of covalent reactive intermediates such as anomeric triflates." @default.
- W2580457814 created "2017-02-03" @default.
- W2580457814 creator A5017608631 @default.
- W2580457814 creator A5054285452 @default.
- W2580457814 creator A5057071421 @default.
- W2580457814 creator A5066491418 @default.
- W2580457814 creator A5078406609 @default.
- W2580457814 date "2017-01-27" @default.
- W2580457814 modified "2023-10-17" @default.
- W2580457814 title "Stereoselective Glycosylations - Additions to Oxocarbenium Ions" @default.
- W2580457814 cites W1155980999 @default.
- W2580457814 cites W1539276553 @default.
- W2580457814 cites W1967468522 @default.
- W2580457814 cites W1968496457 @default.
- W2580457814 cites W1975339286 @default.
- W2580457814 cites W1975878337 @default.
- W2580457814 cites W1977822664 @default.
- W2580457814 cites W1980125142 @default.
- W2580457814 cites W1980436908 @default.
- W2580457814 cites W1990536012 @default.
- W2580457814 cites W1993004564 @default.
- W2580457814 cites W1998287419 @default.
- W2580457814 cites W1999519252 @default.
- W2580457814 cites W2014814139 @default.
- W2580457814 cites W2014892820 @default.
- W2580457814 cites W2016059502 @default.
- W2580457814 cites W2021465763 @default.
- W2580457814 cites W2022673202 @default.
- W2580457814 cites W2023389027 @default.
- W2580457814 cites W2025622555 @default.
- W2580457814 cites W2025708871 @default.
- W2580457814 cites W2029651198 @default.
- W2580457814 cites W2031981183 @default.
- W2580457814 cites W2040415005 @default.
- W2580457814 cites W2041726370 @default.
- W2580457814 cites W2043142753 @default.
- W2580457814 cites W2046971493 @default.
- W2580457814 cites W2048891859 @default.
- W2580457814 cites W2049225087 @default.
- W2580457814 cites W2052377343 @default.
- W2580457814 cites W2062742819 @default.
- W2580457814 cites W2063981461 @default.
- W2580457814 cites W2073271788 @default.
- W2580457814 cites W2073549466 @default.
- W2580457814 cites W2077482030 @default.
- W2580457814 cites W2078166544 @default.
- W2580457814 cites W2079756959 @default.
- W2580457814 cites W2083294340 @default.
- W2580457814 cites W2084197942 @default.
- W2580457814 cites W2084391380 @default.
- W2580457814 cites W2096666086 @default.
- W2580457814 cites W2109481376 @default.
- W2580457814 cites W2115516366 @default.
- W2580457814 cites W2120193168 @default.
- W2580457814 cites W2129122341 @default.
- W2580457814 cites W2155715825 @default.
- W2580457814 cites W2156184601 @default.
- W2580457814 cites W2159190877 @default.
- W2580457814 cites W2159857404 @default.
- W2580457814 cites W2163150937 @default.
- W2580457814 cites W2256783395 @default.
- W2580457814 cites W2312383270 @default.
- W2580457814 cites W2319240408 @default.
- W2580457814 cites W2322306866 @default.
- W2580457814 cites W2323482902 @default.
- W2580457814 cites W2324812274 @default.
- W2580457814 cites W2328383021 @default.
- W2580457814 cites W2333044877 @default.
- W2580457814 cites W2333229079 @default.
- W2580457814 cites W2409474496 @default.
- W2580457814 cites W2490978295 @default.
- W2580457814 cites W2500362940 @default.
- W2580457814 cites W2950235090 @default.
- W2580457814 cites W2951181761 @default.
- W2580457814 cites W2951278590 @default.
- W2580457814 cites W2951712903 @default.
- W2580457814 cites W2952240019 @default.
- W2580457814 cites W2953072844 @default.
- W2580457814 cites W3004582312 @default.
- W2580457814 cites W4247468358 @default.
- W2580457814 cites W4253499407 @default.
- W2580457814 cites W4254774664 @default.
- W2580457814 cites W4362215240 @default.
- W2580457814 doi "https://doi.org/10.1002/9783527696239.ch1" @default.
- W2580457814 hasPublicationYear "2017" @default.
- W2580457814 type Work @default.
- W2580457814 sameAs 2580457814 @default.
- W2580457814 citedByCount "3" @default.
- W2580457814 countsByYear W25804578142018 @default.
- W2580457814 countsByYear W25804578142020 @default.
- W2580457814 countsByYear W25804578142021 @default.
- W2580457814 crossrefType "other" @default.
- W2580457814 hasAuthorship W2580457814A5017608631 @default.
- W2580457814 hasAuthorship W2580457814A5054285452 @default.
- W2580457814 hasAuthorship W2580457814A5057071421 @default.
- W2580457814 hasAuthorship W2580457814A5066491418 @default.
- W2580457814 hasAuthorship W2580457814A5078406609 @default.
- W2580457814 hasConcept C142724271 @default.