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- W2580526064 abstract "Significant changes in the thickness of poly(N-isopropylacrylamide) solid ultrathin films have been observed by X-ray reflectivity as a result of changing the temperature between 15 and 60 °C in an uncontrolled atmosphere. As the property of the film switches between hydrophobic and hydrophilic nature at around 33 °C, the present letter reports that an ultrathin film of around 200 Å exhibits nearly a 7% change in thickness even in an ordinary atmosphere and that cooling and heating exhibit different dependence; i.e., one can confirm the switching point in the cooling run, but the dependence is linear in the heating run. The phenomena are reproducible and repeatable. The thermoresponsive behaviors of PNIPAM solid ultrathin film have been first observed with temperature cycle under ordinary atmospheric conditions. Different transition processes have been confirmed with thickness change, thickness increase with LCST-type switching in cooling run and mono thickness decrease in heating run, which can be explained by switching nature of PNIPAM and limited water in this system." @default.
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- W2580526064 date "2017-04-05" @default.
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- W2580526064 title "Thermoresponsive Behavior of Poly(<i>N</i>-isopropylacrylamide) Solid Ultrathin Film under Ordinary Atmospheric Conditions" @default.
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- W2580526064 doi "https://doi.org/10.1246/cl.161135" @default.
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