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• W2580575386 abstract "A nucleophilic iron–oxygen oxidant, formed in situ in the reaction between an iron(II)–benzilate complex and O2, oxidatively cleaves the aliphatic C−C bonds of α-hydroxy ketones. In the cleavage reaction, α-hydroxy ketones without any α-C−H bond afford a 1:1 mixture of carboxylic acid and ketone. Isotope labeling studies established that one of the oxygen atoms from dioxygen is incorporated into the carboxylic acid product. Furthermore, the iron(II) complex cleaves an aliphatic C−C bond of 17-α-hydroxyprogesterone affording androstenedione and acetic acid. The O2-dependent aliphatic C−C bond cleavage of α-hydroxy ketones containing no α-C−H bond bears similarity to the lyase activity of the heme enzyme, cytochrome P450 17A1 (CYP17A1)." @default.
• W2580575386 created "2017-02-03" @default.
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• W2580575386 date "2017-02-27" @default.
• W2580575386 modified "2023-10-14" @default.
• W2580575386 title "Aliphatic C−C Bond Cleavage in α-Hydroxy Ketones by a Dioxygen-Derived Nucleophilic Iron-Oxygen Oxidant" @default.
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• W2580575386 doi "https://doi.org/10.1002/chem.201605672" @default.
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