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• W25809361 startingPage "549" @default.
• W25809361 abstract "Although the electrochemistry of conducting polymers is now a quite mature subject, there is still considerable debate over most of the basic processes. In part, the issues have been clouded by the diversity of different polymers that have been studied. It is often assumed that conclusions drawn from data on a certain polypyrrole, for example, can be extended to other polypyrroles, polythiophenes, and perhaps other conducting polymers. Although this is often reasonable, it is difficult to maintain awareness of the potential pitfalls. These are compounded by the fact that the same polymer prepared at different times, by different people, or under different conditions, can exhibit significantly different properties. One of the most problematic issues, still to be fully resolved, is the dependence of the degree of oxidation on potential, as measured most commonly by cyclic voltammetry at low scan rates. There is currently no accepted model to describe the shape of the curve and the hysteresis between anodic and cathodic scans. The debate over whether the charge has a significant component due to a polymer/solution double layer is still not fully resolved. However, despite this lack of a basic understanding of the electrochemistry of these materials, much progress has been made in characterizing polymerization mechanisms, degradation processes, transport properties, and the mediation of the electrochemistry of species in solution. These advances have facilitated the development of numerous applications of conducting polymers, and so it can be anticipated that interest in their electrochemistry will remain high." @default.
• W25809361 created "2016-06-24" @default.
• W25809361 creator A5005746309 @default.
• W25809361 date "2002-01-01" @default.
• W25809361 modified "2023-09-27" @default.
• W25809361 title "Electrochemistry of Electronically Conducting Polymer Films" @default.
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