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• W2581167007 startingPage "88" @default.
• W2581167007 abstract "The heat, which is reversibly exchanged at a single electrode, directly correlates with the entropy change during the electrochemical reaction. With recent experimental improvements also surface electrochemical reactions, i.e., reactions with only submonolayer conversion became accessible for heat measurements. Since the reaction entropy includes all side reactions, e.g., also charge–neutral coadsorption or ordering processes of the solvent, it provides complementary information to the current–potential relation, as for example measured by conventional cyclic voltammetry. Here, we will briefly review the theoretical background and recent developments and compare the method to other approaches for the measurement of the entropy of electrochemical systems." @default.
• W2581167007 created "2017-02-03" @default.
• W2581167007 creator A5084765230 @default.
• W2581167007 date "2017-02-01" @default.
• W2581167007 modified "2023-10-02" @default.
• W2581167007 title "Electrochemical microcalorimetry at single electrodes" @default.
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• W2581167007 doi "https://doi.org/10.1016/j.coelec.2017.01.007" @default.
• W2581167007 hasPublicationYear "2017" @default.
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