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• W2581823212 abstract "A novel nanomaterial of MoO2(acac)2 encapsulated in HKUST-1 (MoO2(acac)2@HKUST-1) was conveniently prepared by using the lyophilization method. The material, characterized by several techniques including XRD, N2 physisorption, SEM, FT-IR, XPS UV–Vis DRS and CO-FT-IR, was found to have an enhanced acidity and an additional Lewis acid site different from that in the HKUST-1 crystals. Moreover, the MoO2(acac)2 complexes were uniformly incorporated into the microporous cages of HKUST-1 and the confinement effects provide by the host porous structure significantly decreased the leaching of MoO2(acac)2. As a result, this new catalyst showed efficient catalytic performance and was stable, thus, could be recycled in the epoxidation of soybean oil (SBO) with tert-butyl hydroperoxide (TBHP) as the oxidant in toluene solvent." @default.
• W2581823212 created "2017-02-03" @default.
• W2581823212 creator A5044425176 @default.
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• W2581823212 date "2017-05-01" @default.
• W2581823212 modified "2023-09-29" @default.
• W2581823212 title "Lyophilization-based synthesis of HKUST-1 encapsulated molybdenyl acetylacetonate nanocrystals: An effective soybean oil epoxidation catalyst" @default.
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• W2581823212 doi "https://doi.org/10.1016/j.catcom.2016.11.025" @default.
• W2581823212 hasPublicationYear "2017" @default.
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