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• W2582334138 abstract "ABSTRACT A series of 2‐(1‐(2,4‐dibenzhydrylnaphthylimino)ethyl)‐6‐(1‐(arylimino)ethyl)pyridyliron(II) complexes ( Fe1 − Fe5 ) was synthesized and characterized. The molecular structure of the representative Fe2 was determined by single‐crystal X‐ray diffraction, revealing a distorted pseudo‐square‐pyramidal geometry around the iron center. On activation with either methylaluminoxane (MAO) or modified methylaluminoxane (MMAO), all these iron complex precatalysts performed with high activities (up to 1.58 × 10 7 g (PE) mol −1 (Fe) h −1 ) toward ethylene polymerization, producing highly linear polyethylenes with high molecular weight and bimodal distribution, which was in accordance with high temperature 13 C NMR, high T m values ( T m ∼130 °C) and the GPC curves of the obtained polyethylenes. Meanwhile, DFT calculation results also showed the good correlation between net charges on iron and experimental activities. Compared with previous bis(imino)pyridyliron analogues, the current iron complexes containing the benzhydrylnaphthyl groups exhibited relatively higher activities and better thermal‐stability at elevated temperatures, especially at 80 °C as the industrial operating temperature, and still showed high activities toward ethylene polymerization up to 8.57 × 10 6 g (PE) mol −1 (Fe) h −1 in the presence of co‐catalyst MMAO. In addition, these iron complex precatalysts all exhibited long lifetimes. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55 , 988–996" @default.
• W2582334138 created "2017-02-03" @default.
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• W2582334138 date "2017-01-24" @default.
• W2582334138 modified "2023-10-16" @default.
• W2582334138 title "Activity and stability spontaneously enhanced toward ethylene polymerization by employing 2-(1-(2,4-dibenzhydrylnaphthylimino)ethyl)-6-(1-(arylimino)ethyl) pyridyliron(II) dichlorides" @default.
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• W2582334138 cites W1965708888 @default.
• W2582334138 cites W1965968159 @default.
• W2582334138 cites W1966061406 @default.
• W2582334138 cites W1966792574 @default.
• W2582334138 cites W1968569128 @default.
• W2582334138 cites W1968952002 @default.
• W2582334138 cites W1973274456 @default.
• W2582334138 cites W1973718662 @default.
• W2582334138 cites W1976943363 @default.
• W2582334138 cites W1977371047 @default.
• W2582334138 cites W1978829998 @default.
• W2582334138 cites W1979770220 @default.
• W2582334138 cites W1979776860 @default.
• W2582334138 cites W1985583109 @default.
• W2582334138 cites W1986267883 @default.
• W2582334138 cites W1987586122 @default.
• W2582334138 cites W1989519118 @default.
• W2582334138 cites W1990249417 @default.
• W2582334138 cites W1995815400 @default.
• W2582334138 cites W1996843768 @default.
• W2582334138 cites W2000926258 @default.
• W2582334138 cites W2001445264 @default.
• W2582334138 cites W2002935022 @default.
• W2582334138 cites W2008635776 @default.
• W2582334138 cites W2014347496 @default.
• W2582334138 cites W2014432431 @default.
• W2582334138 cites W2021334014 @default.
• W2582334138 cites W2021911875 @default.
• W2582334138 cites W2025052266 @default.
• W2582334138 cites W2025177757 @default.
• W2582334138 cites W2025576141 @default.
• W2582334138 cites W2037907552 @default.
• W2582334138 cites W2040426412 @default.
• W2582334138 cites W2040569466 @default.
• W2582334138 cites W2043327592 @default.
• W2582334138 cites W2044663447 @default.
• W2582334138 cites W2048160335 @default.
• W2582334138 cites W2049079467 @default.
• W2582334138 cites W2050880541 @default.
• W2582334138 cites W2055289896 @default.
• W2582334138 cites W2057812572 @default.
• W2582334138 cites W2058994509 @default.
• W2582334138 cites W2059165811 @default.
• W2582334138 cites W2060591145 @default.
• W2582334138 cites W2060966918 @default.
• W2582334138 cites W2069778813 @default.
• W2582334138 cites W2071680604 @default.
• W2582334138 cites W2079764602 @default.
• W2582334138 cites W2083864614 @default.
• W2582334138 cites W2084408143 @default.
• W2582334138 cites W2085560435 @default.
• W2582334138 cites W2087183014 @default.
• W2582334138 cites W2090403788 @default.
• W2582334138 cites W2094217156 @default.
• W2582334138 cites W2113755836 @default.
• W2582334138 cites W2152451423 @default.
• W2582334138 cites W2169494038 @default.
• W2582334138 cites W2171608865 @default.
• W2582334138 cites W2172397201 @default.
• W2582334138 cites W2247687558 @default.
• W2582334138 cites W2297771795 @default.
• W2582334138 cites W2298986678 @default.
• W2582334138 cites W2305440968 @default.
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• W2582334138 cites W2328434728 @default.
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• W2582334138 doi "https://doi.org/10.1002/pola.28459" @default.
• W2582334138 hasPublicationYear "2017" @default.
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