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- W2582855376 abstract "ABSTRACT In this work, an octadecylamine‐modified graphene oxide (ODA‐GO)‐MgCl‐supported Ziegler–Natta catalyst was synthesized by reacting ODA‐GO with a Grignard reagent, followed by anchoring TiCl 4 to the structure. The effect of the ODA‐GO on the catalyst morphology and ethylene polymerization behavior was examined. The resultant polyethylene (PE)/ODA‐GO nanocomposites directly mirrored the catalyst morphology by forming a layered morphology, and the ODA‐GO fillers were well dispersed in the PE matrix and showed strong interfacial adhesion with it. The resultant PE/ODA‐GO nanocomposites exhibited better thermal stability and mechanical properties than neat PE, even with a small amount of ODA‐GO added. Thus, this work provides a facile approach to the production of high‐performance PE. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55 , 855–860" @default.
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- W2582855376 date "2017-01-28" @default.
- W2582855376 modified "2023-10-16" @default.
- W2582855376 title "Preparation of Polyethylene/Graphene Nanocomposites with Octadecylamine-Modified Graphene Oxide-MgCl-Supported Ziegler-Natta Catalyst" @default.
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- W2582855376 doi "https://doi.org/10.1002/pola.28437" @default.
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