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• W2582988892 abstract "A stimuli-responsive tetranuclear complex was assembled into new aggregates with controllable dimensionality through directional hydrogen bonds (HBs). A cyanide-bridged tetranuclear complex cation, [Co2 Fe2 (CN)6 (tp*)2 (bpy*)4 ]2+ (abbreviated to 12+ ) (tp*=hydrotris(3,5-dimethylpyrazol-1-yl)borate and bpy*=4,4'-di-methyl-2,2'-bipyridine) has two terminal cyanide nitrogens and acts as a hydrogen-bond acceptor (HBA) with a linear bridging mode. Co-crystallization of 12+ with p-hydroquinone (H2 Q), a hydrogen-bond donor (HBD) with two donor sites, led to a one-dimensional aggregate, 1(BPh4 )2 ⋅(H2 Q)⋅2 H2 O (2), while a two-dimensional sheet with a honeycomb structure, 13 (PF6 )6 ⋅(H3 PG)2 ⋅4 CH3 CN⋅8 H2 O (3), was obtained by co-crystallization with phloroglucinol (H3 PG) acting as a three-way structure-directing HBD. Magnetic measurements revealed that 2 and 3 exhibited thermal and light-induced electron-transfer-coupled spin transitions (ETCSTs)." @default.
• W2582988892 created "2017-02-03" @default.
• W2582988892 creator A5029216071 @default.
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• W2582988892 date "2017-02-06" @default.
• W2582988892 modified "2023-10-17" @default.
• W2582988892 title "Dimensionally Controlled Assembly of an External Stimuli-Responsive [Co₂ Fe₂ ] Complex into Supramolecular Hydrogen-Bonded Networks" @default.
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• W2582988892 doi "https://doi.org/10.1002/chem.201605817" @default.
• W2582988892 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28111822" @default.
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