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- W2583708909 abstract "Rigid polymer backbones have often been considered to be detrimental to the packing of mesogenic pendants, and polyacetylenes have generally been regarded as unpromising materials for light-emitting applications. Our group, however, has succeeded in creating a series of liquid-crystalline polyacetylenes with rigid backbones and a variety of light-emitting polyacetylenes with luminescent chromophores. Here we demonstrate that the rigid polyacetylene skeleton can play a constructive role in guiding the alignments of mesogenic pendants and prove that polyacetylenes can be highly emissive with photoluminescence quantum yields of up to 98% and electroluminescence performances comparable or superior to those of the best blue-light-emitting polymers. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2607–2629, 2003" @default.
- W2583708909 created "2017-02-10" @default.
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- W2583708909 date "2002-01-01" @default.
- W2583708909 modified "2023-09-26" @default.
- W2583708909 title "Liquid Crystalline and Light Emitting Polyacetylenes" @default.
- W2583708909 hasPublicationYear "2002" @default.
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