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- W2584555098 abstract "Abstract Seven new complexes comprising of diosmium(I) tetracarbonyl sawhorse units bound to dicarboxylate anions (DCAs) have been synthesized using microwave heating. Succinic, adipic, pimelic, suberic, tetradecanedioic, and terephthalic acids react with Os 3 (CO) 12 at temperatures ranging from 180 to 205 °C for 12–20 min to produce the osmium sawhorse complexes, which are subsequently reacted with phosphine ligands to replace the labile axial CO ligands. X-ray crystallographic analysis was used to determine the molecular structures of these complexes. Two complexes, those with suberato and tetradecanedioato ligands, are dinuclear species containing Os 2 sawhorse molecules with chelating DCAs that form intramolecular loops. The succinato, adipato and pimelato complexes are tetranuclear species consisting of two Os 2 sawhorse moieties linked together by two bridging DCAs. Thus the straight-chain hydrocarbon backbone of the DCAs must contain at least six carbon atoms in order for these ligands to prefer to chelate a single Os 2 unit instead of forming bridges between multiple Os 2 units. The terephthalato complex is a triangular hexanuclear species consisting of a trimer of dimers with three bridging dicarboxylato anions." @default.
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- W2584555098 date "2017-11-01" @default.
- W2584555098 modified "2023-09-24" @default.
- W2584555098 title "Dicarboxylato ligands in osmium carbonyl sawhorse clusters: Chelating vs. bridging" @default.
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- W2584555098 doi "https://doi.org/10.1016/j.jorganchem.2017.01.026" @default.
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