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- W2585172016 endingPage "2775" @default.
- W2585172016 startingPage "2772" @default.
- W2585172016 abstract "Complex [PtMe2 (PMe2 ArDipp2 )] (1), which contains a tethered terphenyl phosphine (ArDipp2 =2,6-(2,6-i Pr2 C6 H3 )2 C6 H3 ), reacts with [H(Et2 O)2 ]BArF (BArF- =B[3,5-(CF3 )2 C6 H3 ]4- ) to give the solvent (S) complex [PtMe(S)(PMe2 ArDipp2 )]+ (2⋅S). Although the solvent molecule is easily displaced by a Lewis base (e.g., CO or C2 H4 ) to afford the corresponding adducts, treatment of 2⋅S with C2 H2 yielded instead the allyl complex [Pt(η3 -C3 H5 )(PMe2 ArDipp2 )]+ (6) via the alkyne intermediate [PtMe(η2 -C2 H2 )(PMe2 ArDipp2 )]+ (5). Deuteration experiments with C2 D2 , and kinetic and theoretical investigations demonstrated that the conversion of 5 into 6 involves a PtII -promoted HC≡CH to :C=CH2 tautomerization in preference over acetylene migratory insertion into the Pt-Me bond." @default.
- W2585172016 created "2017-02-10" @default.
- W2585172016 creator A5013241624 @default.
- W2585172016 creator A5042292311 @default.
- W2585172016 creator A5042723156 @default.
- W2585172016 creator A5058217052 @default.
- W2585172016 creator A5079090983 @default.
- W2585172016 creator A5091911444 @default.
- W2585172016 date "2017-01-31" @default.
- W2585172016 modified "2023-10-16" @default.
- W2585172016 title "A Cationic Unsaturated Platinum(II) Complex that Promotes the Tautomerization of Acetylene to Vinylidene" @default.
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