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- W2585280882 abstract "The discovery of NdFeB permanent magnets helps to perform technologies with reduced weight and gives them access to miniaturization. The industrial process of production of the Nd-Fe alloy by electrolysis used to manufacture of NdFeB magnets consists in reducing Nd3+ ions dissolved in a LiF-NdF3-Nd2O3 salt on iron cathode at 1050 °C. This route was chosen since the electroplating of neodymium at low temperature molten chloride leads to low recovery yields. This is usually attributed to the comproportionation reaction between the electrodeposited metal and its chloride salt (NdCl3) leading to the formation of NdCl2. In this work, the neodymium electrochemical behavior is reviewed in order to understand its reduction mechanism. Meal addition to LiCl-KCl-NdCl3 melt is usually used to simulated comproportionation reaction in solution. Neodymium deposition yields are studied. Stability of Nd2+ in two different solvent (LiCl-KCl and LiCl) is also discussed through electrodeposition tests on the gram scale." @default.
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- W2585280882 date "2017-01-01" @default.
- W2585280882 modified "2023-10-18" @default.
- W2585280882 title "Electrochemical Behavior of Neodymium in Molten Chloride Salts" @default.
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- W2585280882 doi "https://doi.org/10.1007/978-3-319-51085-9_8" @default.
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