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• W2586634033 endingPage "2074" @default.
• W2586634033 startingPage "2067" @default.
• W2586634033 abstract "Generally, surfactants (or amphiphiles) are believed to be necessary components of microemulsions. However, it has been demonstrated that, in the absence of traditional surfactants, microemulsions can also form from a ternary system of two immiscible fluids (i.e., oil and water phases) and an amphi-solvent, but the current understanding of such surfactant-free microemulsions (SFMEs) is very limited. Herein, we report an SFME consisting of the hydrophobic ionic liquid (IL) 1-butyl-3-methylimidazolium hexafluorophosphate (bmimPF6), the protic IL propylamine nitrate (PAN), and water, in which bmimPF6 and PAN are used as the oil phase and the amphi-solvent, respectively. The microstructures and structural transitions of the SFME were investigated using cyclic voltammetry, fluorescence spectroscopy, and ultraviolet-visible spectroscopy. The SFME exhibited water-in-bmimPF6 (W/IL), bicontinuous (BC), and bmimPF6-in-water (IL/W) microstructures, depending on the composition of the ternary system, similar to the case of traditional surfactant-based microemulsions (SBMEs). The three kinds of microstructures were confirmed by cryogenic transmission electron microscopy (cryo-TEM) observations. To the best of our knowledge, this is the first report on SFMEs composed of two ILs as components, especially where one is used as the amphi-solvent." @default.
• W2586634033 created "2017-02-17" @default.
• W2586634033 creator A5011392215 @default.
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• W2586634033 date "2017-01-01" @default.
• W2586634033 modified "2023-10-02" @default.
• W2586634033 title "Surfactant-free microemulsions of 1-butyl-3-methylimidazolium hexafluorophosphate, propylamine nitrate, and water" @default.
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• W2586634033 doi "https://doi.org/10.1039/c7sm00155j" @default.
• W2586634033 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28217785" @default.
• W2586634033 hasPublicationYear "2017" @default.
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