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• W2586907034 abstract "The structure and configuration of the series of previously unknown arylaminomethylidenefuran‐2(3 H )‐ones have been determined in solution by 1 H, 13 C, 15 N nuclear magnetic resonance spectroscopy including two‐dimensional experiments such as 1 H─ 1 H COSY, dqCOSY, 1 H─ 13 C HSQC, 1 H─ 13 C HMBC. It was found that synthesized substances exist as an equilibrium mixture of E ‐ and Z ‐enamines in solution. It was established on the basis of density functional theory calculations that the exchange between the two push–pull enamines is a simple rotation around an exocyclic partial double bond that depends on the effect of the solvents. Copyright © 2017 John Wiley & Sons, Ltd." @default.
• W2586907034 created "2017-02-17" @default.
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• W2586907034 date "2017-03-20" @default.
• W2586907034 modified "2023-09-27" @default.
• W2586907034 title "Study of <i>E/Z</i> isomerization of (arylamino)methylidenefuran-2(<i>3H</i> )-ones by ¹ H, ¹³ C, ¹⁵ N spectroscopy and DFT calculations in different solvents" @default.
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• W2586907034 doi "https://doi.org/10.1002/mrc.4583" @default.
• W2586907034 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28181284" @default.
• W2586907034 hasPublicationYear "2017" @default.
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