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- W2587016857 abstract "The structural properties of oxygen-deficient ${mathrm{YBa}}_{2}$${mathrm{Cu}}_{3}$${mathrm{O}}_{7mathrm{ensuremath{-}}mathrm{ensuremath{delta}}}$ have been determined by neutron powder diffraction for 0.07<ensuremath{delta}<0.91. The samples were produced by quenching into liquid nitrogen from controlled oxygen partial pressures at 520 ifmmode^circelsetextdegreefi{}C, and they exhibit a clearly defined ``plateau'' behavior of ${T}_{c}$ versus ensuremath{delta}. Superconductivity disappears at the orthorhombic-to-tetragonal transition that occurs near ensuremath{delta}=0.65. Structural parameters, including the copper-oxygen bond lengths, vary smoothly with ensuremath{delta} within each phase but exhibit different behavior in the superconducting and nonsuperconducting phases. These observations are consistent with a model in which superconducting behavior is controlled by charge transfer between the conducting two-dimensional ${mathrm{CuO}}_{2}$ planes and the ${mathrm{CuO}}_{mathrm{x}}$ chains, which act as reservoirs of charge." @default.
- W2587016857 created "2017-02-17" @default.
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- W2587016857 date "1990-02-01" @default.
- W2587016857 modified "2023-10-04" @default.
- W2587016857 title "Structural properties of oxygen-deficient<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>YBa</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Cu</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><…" @default.
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- W2587016857 doi "https://doi.org/10.1103/physrevb.41.1863" @default.
- W2587016857 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/9993913" @default.
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