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• W2587499449 startingPage "3389" @default.
• W2587499449 abstract "Catalytic C(sp3 )-O bond cleavage promoted by B(C6 F5 )3 /Et3 SiH proceeds preferentially with primary tosylates in the presence of primary and secondary silyl ethers and aryl ethers. This reactivity difference enables the chemoselective defunctionalization of several 1,n-diols, and the efficiency of the new procedure is highlighted by the selective deoxygenation of the hydroxymethyl group of an orthogonally protected carbohydrate. Tosylates with an adjacent phenyl group are cleaved with anchimeric assistance." @default.
• W2587499449 created "2017-02-17" @default.
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• W2587499449 creator A5004644359 @default.
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• W2587499449 date "2017-02-09" @default.
• W2587499449 modified "2023-10-11" @default.
• W2587499449 title "B(C₆F₅)₃-Catalyzed Chemoselective Defunctionalization of Ether-Containing Primary Alkyl Tosylates with Hydrosilanes" @default.
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• W2587499449 doi "https://doi.org/10.1002/anie.201611813" @default.
• W2587499449 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28181397" @default.
• W2587499449 hasPublicationYear "2017" @default.
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