Matches in SemOpenAlex for { <https://semopenalex.org/work/W2587757332> ?p ?o ?g. }
- W2587757332 endingPage "1459" @default.
- W2587757332 startingPage "1448" @default.
- W2587757332 abstract "Abstract Copper species have been incorporated in mesoporous silica (MS) through complexation with the amine groups of dodecylamine, which was used as a structure‐directing agent in the synthesis. A series of Cu/SiO 2 catalysts ( x Cu‐MS) with copper loadings ( x ) from 2.5 to 20 wt % was synthesized and evaluated in the gas‐phase hydrogenation of furfural (FUR). The most suitable catalytic performance in terms of 2‐methylfuran yield was obtained with an intermediate copper content (10 wt %). This 10Cu‐MS catalyst exhibits a 2‐methylfuran yield higher than 95 mol % after 5 h time‐on‐stream (TOS) at a reaction temperature of 210 °C with a H 2 /FUR molar ratio of 11.5 and a weight hourly space velocity (WHSV) of 1.5 h −1 . After 14 h TOS, this catalyst still showed a yield of 80 mol %. In all cases, carbonaceous deposits on the external surface were the cause of the catalyst deactivation, although sintering of the copper particles was observed for higher copper loadings. This intermediate copper loading (10 wt %) offered a suitable balance between resistance to sintering and tendency to form carbonaceous deposits." @default.
- W2587757332 created "2017-02-17" @default.
- W2587757332 creator A5024078200 @default.
- W2587757332 creator A5028699318 @default.
- W2587757332 creator A5072282223 @default.
- W2587757332 creator A5090087756 @default.
- W2587757332 date "2017-03-22" @default.
- W2587757332 modified "2023-10-11" @default.
- W2587757332 title "Selective Production of 2-Methylfuran by Gas-Phase Hydrogenation of Furfural on Copper Incorporated by Complexation in Mesoporous Silica Catalysts" @default.
- W2587757332 cites W1966791323 @default.
- W2587757332 cites W1967361991 @default.
- W2587757332 cites W1970497815 @default.
- W2587757332 cites W1971467295 @default.
- W2587757332 cites W1978934992 @default.
- W2587757332 cites W1980317218 @default.
- W2587757332 cites W1980704616 @default.
- W2587757332 cites W1983080679 @default.
- W2587757332 cites W1983602603 @default.
- W2587757332 cites W1984935933 @default.
- W2587757332 cites W1987643155 @default.
- W2587757332 cites W2002860982 @default.
- W2587757332 cites W2006773231 @default.
- W2587757332 cites W2007540026 @default.
- W2587757332 cites W2015497282 @default.
- W2587757332 cites W2021937672 @default.
- W2587757332 cites W2025323283 @default.
- W2587757332 cites W2025842660 @default.
- W2587757332 cites W2040432202 @default.
- W2587757332 cites W2043232342 @default.
- W2587757332 cites W2044739989 @default.
- W2587757332 cites W2044994929 @default.
- W2587757332 cites W2045188385 @default.
- W2587757332 cites W2046705445 @default.
- W2587757332 cites W2054059669 @default.
- W2587757332 cites W2058269497 @default.
- W2587757332 cites W2058869761 @default.
- W2587757332 cites W2061177454 @default.
- W2587757332 cites W2061262587 @default.
- W2587757332 cites W2064911997 @default.
- W2587757332 cites W2067242309 @default.
- W2587757332 cites W2069019799 @default.
- W2587757332 cites W2075513979 @default.
- W2587757332 cites W2077066244 @default.
- W2587757332 cites W2086953172 @default.
- W2587757332 cites W2088956063 @default.
- W2587757332 cites W2091261887 @default.
- W2587757332 cites W2093926490 @default.
- W2587757332 cites W2109393147 @default.
- W2587757332 cites W2111586715 @default.
- W2587757332 cites W2113885387 @default.
- W2587757332 cites W2120468444 @default.
- W2587757332 cites W2139084999 @default.
- W2587757332 cites W2140666105 @default.
- W2587757332 cites W2143717100 @default.
- W2587757332 cites W2152379942 @default.
- W2587757332 cites W2163303403 @default.
- W2587757332 cites W2163446140 @default.
- W2587757332 cites W2163642090 @default.
- W2587757332 cites W2165032076 @default.
- W2587757332 cites W2169938000 @default.
- W2587757332 cites W2197882497 @default.
- W2587757332 cites W2238351122 @default.
- W2587757332 cites W2262231505 @default.
- W2587757332 cites W2297294813 @default.
- W2587757332 cites W2302062736 @default.
- W2587757332 cites W2317714985 @default.
- W2587757332 cites W2327692523 @default.
- W2587757332 cites W2988745314 @default.
- W2587757332 doi "https://doi.org/10.1002/cssc.201700086" @default.
- W2587757332 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28165200" @default.
- W2587757332 hasPublicationYear "2017" @default.
- W2587757332 type Work @default.
- W2587757332 sameAs 2587757332 @default.
- W2587757332 citedByCount "48" @default.
- W2587757332 countsByYear W25877573322017 @default.
- W2587757332 countsByYear W25877573322018 @default.
- W2587757332 countsByYear W25877573322019 @default.
- W2587757332 countsByYear W25877573322020 @default.
- W2587757332 countsByYear W25877573322021 @default.
- W2587757332 countsByYear W25877573322022 @default.
- W2587757332 countsByYear W25877573322023 @default.
- W2587757332 crossrefType "journal-article" @default.
- W2587757332 hasAuthorship W2587757332A5024078200 @default.
- W2587757332 hasAuthorship W2587757332A5028699318 @default.
- W2587757332 hasAuthorship W2587757332A5072282223 @default.
- W2587757332 hasAuthorship W2587757332A5090087756 @default.
- W2587757332 hasConcept C127413603 @default.
- W2587757332 hasConcept C131779359 @default.
- W2587757332 hasConcept C134121241 @default.
- W2587757332 hasConcept C13965031 @default.
- W2587757332 hasConcept C161790260 @default.
- W2587757332 hasConcept C178790620 @default.
- W2587757332 hasConcept C179104552 @default.
- W2587757332 hasConcept C185592680 @default.
- W2587757332 hasConcept C191897082 @default.
- W2587757332 hasConcept C192562407 @default.
- W2587757332 hasConcept C2777496208 @default.
- W2587757332 hasConcept C2777581544 @default.