FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2587881688> ?p ?o ?g. }

• W2587881688 abstract "Recent literature reports have shown the ability to manipulate Cu-Zn cation ordering for Cu2ZnSnSe4 (CZTSe) via low temperature treatments. Theoretical arguments suggest that one of the major roadblocks to higher VOC—significant band tailing—could be improved with increased cation order; however, few direct measurements have been reported and significant device improvements have not yet been realized. This report investigates electrical properties, defects, and devices from quenched and slow-cooled single crystals of CZTSe. The extent of disorder was characterized by Raman spectroscopy as well as x-ray diffraction, where the change in Cu-Zn order can be detected by a changing c/a ratio. Quenched samples show higher acceptor concentrations, lower hole mobilities, and a lower-energy photoluminescence (PL) peak than crystals cooled at slower rates, consistent with a reduction in the bandgap. In addition, samples quenched at the highest temperatures showed lower PL yield consistent with higher quantities of deep defects. Devices fabricated using slow-cooled CZTSe single crystals showed improved efficiencies, most notably with increased VOC; however, low temperature intensity-dependent photoluminescence measurements continue to indicate the existence of potential fluctuations. We discuss the possibility that potential fluctuations in slow-cooled samples may be related to the inability to achieve a long range order of the Cu-Zn sub-lattice resulting in local regions of high and low levels of cation order, and consequent local variations in the bandgap. The presence of significant potential fluctuations, even after the slow-cooling step, suggests the difficulty in eliminating band-tailing in this system, and thus, additional approaches may be needed for significant reduction of the VOC deficit." @default.
• W2587881688 created "2017-02-24" @default.
• W2587881688 creator A5005109790 @default.
• W2587881688 creator A5009085067 @default.
• W2587881688 creator A5045990554 @default.
• W2587881688 creator A5056893237 @default.
• W2587881688 creator A5061521358 @default.
• W2587881688 creator A5070171280 @default.
• W2587881688 date "2017-02-13" @default.
• W2587881688 modified "2023-09-27" @default.
• W2587881688 title "Modification of defects and potential fluctuations in slow-cooled and quenched Cu2ZnSnSe4 single crystals" @default.
• W2587881688 cites W1542154975 @default.
• W2587881688 cites W1590304507 @default.
• W2587881688 cites W1963991749 @default.
• W2587881688 cites W1979583260 @default.
• W2587881688 cites W1988676172 @default.
• W2587881688 cites W1993210824 @default.
• W2587881688 cites W1994408743 @default.
• W2587881688 cites W1995113380 @default.
• W2587881688 cites W1996515894 @default.
• W2587881688 cites W2003008821 @default.
• W2587881688 cites W2005393401 @default.
• W2587881688 cites W2017721885 @default.
• W2587881688 cites W2022097197 @default.
• W2587881688 cites W2023572067 @default.
• W2587881688 cites W2041351054 @default.
• W2587881688 cites W2045315502 @default.
• W2587881688 cites W2062058286 @default.
• W2587881688 cites W2063127218 @default.
• W2587881688 cites W2072681751 @default.
• W2587881688 cites W2116671038 @default.
• W2587881688 cites W2141410697 @default.
• W2587881688 cites W2146825023 @default.
• W2587881688 cites W2310627432 @default.
• W2587881688 cites W2323483469 @default.
• W2587881688 cites W2330817760 @default.
• W2587881688 cites W2331586104 @default.
• W2587881688 doi "https://doi.org/10.1063/1.4975483" @default.
• W2587881688 hasPublicationYear "2017" @default.
• W2587881688 type Work @default.
• W2587881688 sameAs 2587881688 @default.
• W2587881688 citedByCount "15" @default.
• W2587881688 countsByYear W25878816882018 @default.
• W2587881688 countsByYear W25878816882019 @default.
• W2587881688 countsByYear W25878816882020 @default.
• W2587881688 countsByYear W25878816882021 @default.
• W2587881688 countsByYear W25878816882022 @default.
• W2587881688 countsByYear W25878816882023 @default.
• W2587881688 crossrefType "journal-article" @default.
• W2587881688 hasAuthorship W2587881688A5005109790 @default.
• W2587881688 hasAuthorship W2587881688A5009085067 @default.
• W2587881688 hasAuthorship W2587881688A5045990554 @default.
• W2587881688 hasAuthorship W2587881688A5056893237 @default.
• W2587881688 hasAuthorship W2587881688A5061521358 @default.
• W2587881688 hasAuthorship W2587881688A5070171280 @default.
• W2587881688 hasBestOaLocation W25878816881 @default.
• W2587881688 hasConcept C113196181 @default.
• W2587881688 hasConcept C120665830 @default.
• W2587881688 hasConcept C121332964 @default.
• W2587881688 hasConcept C159467904 @default.
• W2587881688 hasConcept C181966813 @default.
• W2587881688 hasConcept C185592680 @default.
• W2587881688 hasConcept C192562407 @default.
• W2587881688 hasConcept C207114421 @default.
• W2587881688 hasConcept C26873012 @default.
• W2587881688 hasConcept C2779892579 @default.
• W2587881688 hasConcept C40003534 @default.
• W2587881688 hasConcept C43617362 @default.
• W2587881688 hasConcept C49040817 @default.
• W2587881688 hasConcept C85080765 @default.
• W2587881688 hasConceptScore W2587881688C113196181 @default.
• W2587881688 hasConceptScore W2587881688C120665830 @default.
• W2587881688 hasConceptScore W2587881688C121332964 @default.
• W2587881688 hasConceptScore W2587881688C159467904 @default.
• W2587881688 hasConceptScore W2587881688C181966813 @default.
• W2587881688 hasConceptScore W2587881688C185592680 @default.
• W2587881688 hasConceptScore W2587881688C192562407 @default.
• W2587881688 hasConceptScore W2587881688C207114421 @default.
• W2587881688 hasConceptScore W2587881688C26873012 @default.
• W2587881688 hasConceptScore W2587881688C2779892579 @default.
• W2587881688 hasConceptScore W2587881688C40003534 @default.
• W2587881688 hasConceptScore W2587881688C43617362 @default.
• W2587881688 hasConceptScore W2587881688C49040817 @default.
• W2587881688 hasConceptScore W2587881688C85080765 @default.
• W2587881688 hasFunder F4320306084 @default.
• W2587881688 hasIssue "6" @default.
• W2587881688 hasLocation W25878816881 @default.
• W2587881688 hasLocation W25878816882 @default.
• W2587881688 hasLocation W25878816883 @default.
• W2587881688 hasOpenAccess W2587881688 @default.
• W2587881688 hasPrimaryLocation W25878816881 @default.
• W2587881688 hasRelatedWork W1582876162 @default.
• W2587881688 hasRelatedWork W2015410978 @default.
• W2587881688 hasRelatedWork W2025940683 @default.
• W2587881688 hasRelatedWork W2035672708 @default.
• W2587881688 hasRelatedWork W2059174086 @default.
• W2587881688 hasRelatedWork W2087921836 @default.
• W2587881688 hasRelatedWork W2127615426 @default.
• W2587881688 hasRelatedWork W2348373917 @default.
• W2587881688 hasRelatedWork W3021910030 @default.

• next