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• W2587889595 abstract "Hydrogen electrooxidation via a “hydrogen abstraction” mechanism in an aprotic ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl) [Bmpy][NTf2] under anaerobic conditions was investigated using cyclic voltammetry and density functional theory (DFT). It is found that a platinum bound NTf2 radical (NTf2•) formed by the oxidation of NTf2– at anodic potential can catalyze the oxidation of hydrogen and enhance its reaction rate. Both experimental and theoretical studies (DFT) have supported a mechanism involving a NTf2• radical intermediate that catalyzes the hydrogen redox processes." @default.
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• W2587889595 date "2017-03-01" @default.
• W2587889595 modified "2023-10-18" @default.
• W2587889595 title "Hydrogen Electrooxidation in Ionic Liquids Catalyzed by the NTf₂ Radical" @default.
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• W2587889595 doi "https://doi.org/10.1021/acs.jpcc.7b00335" @default.
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