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- W2588349712 abstract "Two flexible, branched, and sterically constrained di- and tripodal side arms around a phenol backbone were utilized in ligands H3L1 and H5L2 to isolate {Mn6} and {Mn3} coordination aggregates. 2,6-Bis{(1-hydroxy-2-methylpropan-2-ylimino)methyl}-4-methylphenol (H3L1) gave trinuclear complex [Mn3(μ-H2L1)2(μ1,3-O2CCH3)4(CH3OH)2](ClO4)2·4CH3OH (1), whereas 2,6-bis[{1-hydroxy-2-(hydroxymethyl)butan-2-ylimino}methyl]-4-methylphenol (H5L2) provided hexanuclear complex [Mn6(μ4-H2L2)2(μ-HL3)2(μ3-OH)2(μ1,3-O2CC2H5)4](ClO4)2·2H2O (2). Binding of acetates and coordination of {H2L1}- provided a linear MnIIIMnIIMnIII arrangement in 1. A MnIII6 fused diadamantane-type assembly was obtained in 2 from propionate bridges, coordination of {H2L2}3-, and in situ generated {HL3}2-. The magnetic characterization of 1 and 2 revealed the properties dominated by intramolecular anti-ferromagnetic exchange interactions, and this was confirmed using density functional theory calculations. Complex 1 exhibited field-induced slow magnetic relaxation at 2 K due to the axial anisotropy of MnIII centers. Both the complexes show effective solvent-dependent catechol oxidation toward 3,5-di-tert-butylcatechol in air. The catechol oxidation abilities are comparable from two complexes of different nuclearity and structure." @default.
- W2588349712 created "2017-02-24" @default.
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- W2588349712 date "2017-02-15" @default.
- W2588349712 modified "2023-10-02" @default.
- W2588349712 title "Dangling and Hydrolyzed Ligand Arms in [Mn<sub>3</sub>] and [Mn<sub>6</sub>] Coordination Assemblies: Synthesis, Characterization, and Functional Activity" @default.
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- W2588349712 cites W1841903237 @default.
- W2588349712 cites W1961714136 @default.
- W2588349712 cites W1964864719 @default.
- W2588349712 cites W1967887562 @default.
- W2588349712 cites W1976196727 @default.
- W2588349712 cites W1990775843 @default.
- W2588349712 cites W2000038903 @default.
- W2588349712 cites W2000516926 @default.
- W2588349712 cites W2000809738 @default.
- W2588349712 cites W2002724434 @default.
- W2588349712 cites W2008090373 @default.
- W2588349712 cites W2010213342 @default.
- W2588349712 cites W2011190695 @default.
- W2588349712 cites W2011821458 @default.
- W2588349712 cites W2013958853 @default.
- W2588349712 cites W2026040063 @default.
- W2588349712 cites W2026673235 @default.
- W2588349712 cites W2026793668 @default.
- W2588349712 cites W2032781086 @default.
- W2588349712 cites W2033619848 @default.
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- W2588349712 cites W2043738901 @default.
- W2588349712 cites W2045952721 @default.
- W2588349712 cites W2047891935 @default.
- W2588349712 cites W2054943147 @default.
- W2588349712 cites W2056199152 @default.
- W2588349712 cites W2056449341 @default.
- W2588349712 cites W2056509210 @default.
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- W2588349712 cites W2087715723 @default.
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- W2588349712 cites W2154864221 @default.
- W2588349712 cites W2156030087 @default.
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- W2588349712 cites W2184381064 @default.
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- W2588349712 cites W2323845875 @default.
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- W2588349712 doi "https://doi.org/10.1021/acs.inorgchem.6b02813" @default.
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