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• W2588580147 abstract "Trifluoromethylthiolation by sulfuration of difluorocarbene with elemental sulfur is described for the first time, which overrides long-standing trifluoromethyl anion-based theory. Mechanistic elucidation reveals an unprecedented chemical process for the formation of thiocarbonyl fluoride and also enables transition-metal-mediated trifluoromethylthiolation and [18 F]trifluoromethylthiolation of α-bromo carbonyl compounds with broad substrate scope and compatibility." @default.
• W2588580147 created "2017-02-24" @default.
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• W2588580147 date "2017-02-14" @default.
• W2588580147 modified "2023-09-25" @default.
• W2588580147 title "An Unconventional Mechanistic Insight into SCF₃Formation from Difluorocarbene: Preparation of¹⁸F-Labeled α-SCF₃Carbonyl Compounds" @default.
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• W2588580147 doi "https://doi.org/10.1002/anie.201611761" @default.
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