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• W2588895546 abstract "The B2Σ- - X2Π3/2(0,0) bands of a cold molecular beam sample of gold monoxide, AuO, and gold monosulfide, AuS, have been recorded at high resolution both field free and in the presence of a static electric field. The observed electric field induced splittings and shifts were analyzed to produce permanent electric dipole moments, μ→el, of 2.94±0.06 D and 2.22±0.05 D for the X2Π3/2(v = 0) states of AuO and AuS, respectively. A molecular orbital correlation diagram is used to rationalize the trend in ground state μ→el values for AuX (X = F, Cl, O, and S) molecules. The experimentally determined μ→el are compared to those computed at the coupled-cluster singles and doubles (CCSD) level augmented with a perturbative inclusion of triple excitations (CCSD(T)) level of theory." @default.
• W2588895546 created "2017-02-24" @default.
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• W2588895546 date "2017-02-13" @default.
• W2588895546 modified "2023-09-28" @default.
• W2588895546 title "The electric dipole moments in the ground states of gold oxide, AuO, and gold sulfide, AuS" @default.
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• W2588895546 doi "https://doi.org/10.1063/1.4975816" @default.
• W2588895546 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28201899" @default.
• W2588895546 hasPublicationYear "2017" @default.
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