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- W2588897202 abstract "Abstract Borylative radical cyclization of benzo[3,4]cyclodec‐3‐ene‐1,5‐diynes to provide 5‐borylated 6,7,8,9‐tetrahydrobenzo[ a ]azulenes has been developed. The experimental results suggest that the reaction proceeds by a radical chain mechanism, in which di‐ tert ‐butyl hyponitrite (TBHN) works as a good radical initiator to form boryl radicals from N‐heterocyclic carbene–boranes (NHC‐boranes). The present reaction is a rare model that illustrates addition of boryl radicals to alkynes." @default.
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- W2588897202 date "2017-03-27" @default.
- W2588897202 modified "2023-10-10" @default.
- W2588897202 title "Borylative Radical Cyclizations of Benzo[3,4]cyclodec‐3‐ene‐1,5‐diynes and N‐Heterocyclic Carbene‐Boranes" @default.
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- W2588897202 doi "https://doi.org/10.1002/chem.201700689" @default.
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