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• W2588970090 abstract "Five stereochemically different 2:1 Diels–Alder adducts were prepared starting with cyclopentadiene and p-benzoquinone. Separately, these adducts were treated with an excess amount of base and allyl bromide to deliver two different tetra-allylated products. These allyl derivatives gave the corresponding mono-propellane derivatives on metathesis sequence. Five Diels–Alder adducts on treatment with Grubbs ruthenium catalysts delivered the corresponding mono- and di-ring-opened metathesis products. Structures of three functionalized adducts were determined by single-crystal X-ray diffraction studies." @default.
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• W2588970090 date "2017-03-01" @default.
• W2588970090 modified "2023-09-24" @default.
• W2588970090 title "Isomerization and functionalization of 2:1 Diels–Alder adducts of cyclopentadiene and p -benzoquinone: Applications to polycycles via ring-closing metathesis and ring-opening metathesis as key steps" @default.
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• W2588970090 doi "https://doi.org/10.1016/j.tetlet.2017.02.039" @default.
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