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• W2588994438 abstract "Abstract Key message This article presents the leaching, fire and weathering resistance improvements of samples treated with tannin-based wood preservatives added of caprolactam. PEG-added formulations show limited applicability. The FT-IR and 13 C-NMR analyses of the caprolactam-added formulations show some evidences of copolymerization. Context Tannin-boron wood preservatives are known for their high resistance against leaching, biological attacks, fire as well as for the good mechanical properties that they impart to wood. These properties promoted these formulations for being a candidate for the protection of green buildings. However, the low elasticity of these polymers and their dark colour implied limited weathering resistances. Aims The aim of the study is to find suitable additives for tannin-based formulations to overcome their limited weathering resistances, without compromising the other properties. Methods Treatment, leaching and fire tests, dimensional stability as well as artificial and natural weathering of the timber treated with caprolactam-added and PEG-added formulations were performed. FT-IR and 13 C-NMR of the formulations were presented. Results The presence of caprolactam improved the properties of the formulation with particularly significant results in terms of resistance against leaching and dimensional stability. These enhancements were imparted also to the weathering resistance of the tannin-caprolactam formulations. Indeed, the colour changes during the artificial and natural exposures were stable for longer periods. FT-IR and 13 C-NMR investigations of the advanced formulations were led, and covalent copolymerization of the caprolactam with the tannin-hexamine polymer was observed. Conclusion The tannin formulations with caprolactam improved the durability of the wood specimens, while the PEG-tannin presented strong application drawbacks." @default.
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• W2588994438 date "2017-02-15" @default.
• W2588994438 modified "2023-10-13" @default.
• W2588994438 title "Tannin-caprolactam and Tannin-PEG formulations as outdoor wood preservatives: weathering properties" @default.
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• W2588994438 doi "https://doi.org/10.1007/s13595-016-0605-y" @default.
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