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- W2589030038 abstract "Abstract 1-Ethyl-3-methylimidazolium acetate is introduced as a robust organocatalyst for solvent-free cyanosilylation of carbonyl compounds with trimethylsilyl cyanide (TMSCN). The catalyst loading can be reduced to as low as 0.1–0.0001 mol % under mild reaction conditions, giving considerably high TOF values from 10,843 h −1 to 10,602,410 h −1 in the field of organocatalyzed transformations. The present protocol not only tolerates with extensive carbonyl compounds but also provides somewhat insight into the mechanism of ionic liquids (ILs)-catalyzed reactions." @default.
- W2589030038 created "2017-02-24" @default.
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- W2589030038 date "2017-02-15" @default.
- W2589030038 modified "2023-10-09" @default.
- W2589030038 title "1-Ethyl-3-methylimidazolium acetate as a highly efficient organocatalyst for cyanosilylation of carbonyl compounds with trimethylsilyl cyanide" @default.
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- W2589030038 doi "https://doi.org/10.1038/srep42699" @default.
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