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- W2589125084 abstract "gem-Dicarboxylic esters in the presence of a lactam moiety were reduced diastereoselectively to the monoalcohol using a catalytic amount of NaBH4 and InCl3. The presence of the lactam group was necessary for an efficient reaction as the absence of the carbonyl moiety on the lactam produced slower reactions in poorer yields. The proposed mechanism involves dichloroindium hydride generated in situ from NaBH4 and a catalytic amount of InCl3, resulting in a stereoselective radical decarboxylation, followed by reduction of the ester to give the monoalcohol." @default.
- W2589125084 created "2017-02-24" @default.
- W2589125084 date "2005-11-22" @default.
- W2589125084 modified "2023-10-14" @default.
- W2589125084 title "Stereoselective Reduction of Dicarboxylic Esters using NaBH4-InCl3" @default.
- W2589125084 doi "https://doi.org/10.1055/s-2005-916137" @default.
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