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- W2589270310 abstract "The underexploited biorenewable p-cymene is employed as a solvent for the metathesis of various substrates. p-Cymene is a nontoxic compound that can be obtained in large amounts as a side product of the cellulose and citrus industry. For the cross-metathesis of estragole with methyl acrylate, this solvent prevents the consecutive double-bond isomerization of the product and affords the best yield of all solvents tested. Undesired consecutive isomerization is a major challenge for many substrates in olefin metathesis, including pharmaceutical precursors, and the use of p-cymene as a solvent may be a way to prevent it. This solvent results in a better metathesis performance than toluene for the three substrates tested in this work, matching its performance for two other substrates." @default.
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- W2589270310 date "2017-03-21" @default.
- W2589270310 modified "2023-09-30" @default.
- W2589270310 title "<i>p</i> -Cymene as Solvent for Olefin Metathesis: Matching Efficiency and Sustainability" @default.
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- W2589270310 doi "https://doi.org/10.1002/cssc.201700116" @default.
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